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学科主题: Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
题名:
Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units
作者: Li Hongyi; Pan ShiLie(潘世烈); Wu Hongping; Smit Jared P.; Poeppelmeier Kenneth R.
通讯作者: Pan, SL
关键词: Oxide materials ; Solid state reactions ; Crystal structure ; X-ray diffraction
刊名: JOURNAL OF ALLOYS AND COMPOUNDS
发表日期: 2011
DOI: 10.1016/j.jallcom.2010.11.206
卷: 509, 期:7, 页:3310-3313
收录类别: SCI
英文摘要:

The copper borate Li2Pb2CuB4O40 has been synthesized in air by the standard solid-state reaction at temperature in the range 550-650 degrees C and the structure of Li2Pb2CuB4O10 was determined by single-crystal X-ray diffraction. Li2Pb2CuB4O10 crystallizes in the monoclinic space group C2/c (no. 15) with a=16.8419(12), b=4.7895(4), c = 13.8976(10)angstrom, and beta = 125.3620(10)degrees, V=914.22(12)angstrom(3), and Z=4, as determined by single-crystal X-ray diffraction. The Li2Pb2CuB4O10 structure exhibits isolated units of stoichiometry [CuB4O10](6-) that are built from CuO4 distorted square planes and triangular BO3 groups. The IR spectroscopy and thermal analysis investigations of Li2Pb2CuB4O10 are also presented.

WOS记录号: WOS:000287570100021
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2796
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

Recommended Citation:
Li Hongyi,Pan Shilie,Wu Hongping,et al. Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2011-01-01,509(7):3310-3313.
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文件名: Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units.pdf
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