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学科主题: Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
题名: Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)(2)
作者: Zhang Min; Pan Shilie; Han Jian; Yang Yun; Cui Liang; Zhou Zhongxiang
通讯作者: Pan, SL
关键词: Ba2Cd(BO3)(2) ; Crystal structure ; Crystal growth ; Borate
刊名: JOURNAL OF ALLOYS AND COMPOUNDS
发表日期: 2011
DOI: 10.1016/j.jallcom.2011.03.141
卷: 509, 期:23, 页:6696-6699
收录类别: SCI
资助者: Chinese Academy of Sciences KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; Xinjiang Uygur Autonomous Region of China 200816120; Urumqi of China G09212001
摘要: A novel dibarium cadmium diborate, Ba2Cd(BO3)(2), has been successfully synthesized by standard solid-state reaction. Large sheet-like crystal with size up to 20mmx15mmx0.7mm has been obtained using top-seed solution growth method. Ba2Cd(BO3)(2) crystallizes in the monoclinic space group C2/m with a = 9.6305(4) angstrom, b = 5.3626(3) angstrom, c = 6.5236(2) angstrom, beta = 118.079(3)degrees, Z = 2. The crystal structure is composed of isolated BO3 triangles, CdO6 octahedra and BaO9 polyhedra. CdO6 are vertex-connected with six BO3 to form infinite (infinity)Cd(B-3)(2) layers extending in (0 0 1) plane, and two rows of Ba atoms closely occupy two side of (infinity)Cd(BO3)(2) layers to forming stoichiometric sheets. IR and transmittance spectrum of Ba2Cd(BO3)(2) were reported.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2766
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Zhang Min,Pan Shilie,Han Jian,et al. Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)(2)[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2011,509(23):6696-6699.
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文件名: growth, crystal structure and optical properties of layered dibarium cadmium diborate, ba2cd(bo3)2.pdf
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