Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)(2)
Zhang Min; Pan Shilie; Han Jian; Yang Yun; Cui Liang; Zhou Zhongxiang
2011
发表期刊JOURNAL OF ALLOYS AND COMPOUNDS
ISSN0925-8388
卷号509期号:23页码:6696-6699
摘要

A novel dibarium cadmium diborate, Ba2Cd(BO3)(2), has been successfully synthesized by standard solid-state reaction. Large sheet-like crystal with size up to 20mmx15mmx0.7mm has been obtained using top-seed solution growth method. Ba2Cd(BO3)(2) crystallizes in the monoclinic space group C2/m with a = 9.6305(4) angstrom, b = 5.3626(3) angstrom, c = 6.5236(2) angstrom, beta = 118.079(3)degrees, Z = 2. The crystal structure is composed of isolated [BO3] triangles, [CdO6] octahedra and [BaO9] polyhedra. CdO6 are vertex-connected with six BO3 to form infinite (infinity)[Cd(B-3)(2)] layers extending in (0 0 1) plane, and two rows of Ba atoms closely occupy two side of (infinity)[Cd(BO3)(2)] layers to forming stoichiometric sheets. IR and transmittance spectrum of Ba2Cd(BO3)(2) were reported.

关键词Ba2cd(Bo3)(2) Crystal Structure Crystal Growth Borate
学科领域Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
DOI10.1016/j.jallcom.2011.03.141
收录类别SCI
WOS记录号WOS:000290304200038
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2766
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Zhang Min,Pan Shilie,Han Jian,et al. Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)(2)[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2011,509(23):6696-6699.
APA Zhang Min,Pan Shilie,Han Jian,Yang Yun,Cui Liang,&Zhou Zhongxiang.(2011).Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)(2).JOURNAL OF ALLOYS AND COMPOUNDS,509(23),6696-6699.
MLA Zhang Min,et al."Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)(2)".JOURNAL OF ALLOYS AND COMPOUNDS 509.23(2011):6696-6699.
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