Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units
Shi Yunjing; Pan Shilie; Dong Xiaoyu; Wang Ying; Zhang Min; Zhang Fangfang; Zhou Zhongxiang
2012
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume51Issue:20Pages:10870-10875
Abstract

A new noncentrosymmetric borophosphate, Na3Cd3B(PO4)(4), has been successfully synthesized by conventional solid state reaction for the first time. It crystallizes in the orthorhombic space group Pmc2(1) with unit cell parameters of a = 13.6854(3) angstrom, b = 5.3346(11) angstrom, c = 18.2169(4) angstrom, and Z = 4. Na3Cd3B(PO4)(4) features zero-dimensional [B(PO4)(4)](9-) anion units with Cd2+ and Na+/Cd2+ cations located around them, in which the BO4 tetrahedron is surrounded by four PO4 tetrahedra by sharing the vertexes of O atoms. Second harmonic generation (SHG) measurements show that Na3Cd3B(PO4)(4) exhibits a SHG response 1.1 times larger than that of KH2PO4 (KDP) and is phase matchable.

Subject AreaChemistry
DOI10.1021/ic301351k
Indexed BySCI
WOS IDWOS:000309739100044
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2762
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Shi Yunjing,Pan Shilie,Dong Xiaoyu,et al. Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units[J]. INORGANIC CHEMISTRY,2012,51(20):10870-10875.
APA Shi Yunjing.,Pan Shilie.,Dong Xiaoyu.,Wang Ying.,Zhang Min.,...&Zhou Zhongxiang.(2012).Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units.INORGANIC CHEMISTRY,51(20),10870-10875.
MLA Shi Yunjing,et al."Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units".INORGANIC CHEMISTRY 51.20(2012):10870-10875.
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