Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7
Dong Lingyun; Pan Shilie; Yang Zhihua; Zhao Wenwu; Dong Xiaoyu; Wang Ying; Huang Yineng
2012
Source PublicationZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
Volume638Issue:14Pages:2280-2285
Abstract

A new compound, Pb6AlB2O7F7, was synthesized from the PbF2/B2O3 flux system, which is the first compound found in the PbF2/Al2O3/B2O3 system. It crystallizes in the orthorhombic system, space group Cmca (No. 64) with unit cell parameters a = 11.649(7) angstrom, b = 18.300(11) angstrom, c = 6.394(4) angstrom, Z = 4. The crystal structure of Pb6AlB2O7F7 contains the group [Pb6BO11F10] as basal building unit, which connects with each other forming two-dimensional (infinity)[Pb6BO11F10] layers, whereas aluminum atoms are filled in the interlayers. The IR spectrum further confirms the presence of BO3 groups. The calculated band structures and the density of states of Pb6AlB2O7F7 suggest that its indirect gap is 2.968 eV. The DSC analysis and X-ray diffraction technique prove that Pb6AlB2O7F7 is a congruent-melting compound.

KeywordPb6alb2o7f7 Borates Synthesis Crystal Structure
Subject AreaChemistry
DOI10.1002/zaac.201200374
Indexed BySCI
WOS IDWOS:000310979300018
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2754
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China; Yili Normal Univ, Xinjiang Lab Phase Transit & Microstruct Condense
Recommended Citation
GB/T 7714
Dong Lingyun,Pan Shilie,Yang Zhihua,et al. Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2012,638(14):2280-2285.
APA Dong Lingyun.,Pan Shilie.,Yang Zhihua.,Zhao Wenwu.,Dong Xiaoyu.,...&Huang Yineng.(2012).Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,638(14),2280-2285.
MLA Dong Lingyun,et al."Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 638.14(2012):2280-2285.
Files in This Item:
File Name/Size DocType Version Access License
Synthesis, Crystal S(463KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Dong Lingyun]'s Articles
[Pan Shilie]'s Articles
[Yang Zhihua]'s Articles
Baidu academic
Similar articles in Baidu academic
[Dong Lingyun]'s Articles
[Pan Shilie]'s Articles
[Yang Zhihua]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Dong Lingyun]'s Articles
[Pan Shilie]'s Articles
[Yang Zhihua]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.