Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7
Dong Lingyun; Pan Shilie; Yang Zhihua; Zhao Wenwu; Dong Xiaoyu; Wang Ying; Huang Yineng; Pan, SL
2012
发表期刊ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
卷号638期号:14页码:2280-2285
摘要

A new compound, Pb6AlB2O7F7, was synthesized from the PbF2/B2O3 flux system, which is the first compound found in the PbF2/Al2O3/B2O3 system. It crystallizes in the orthorhombic system, space group Cmca (No. 64) with unit cell parameters a = 11.649(7) angstrom, b = 18.300(11) angstrom, c = 6.394(4) angstrom, Z = 4. The crystal structure of Pb6AlB2O7F7 contains the group [Pb6BO11F10] as basal building unit, which connects with each other forming two-dimensional (infinity)[Pb6BO11F10] layers, whereas aluminum atoms are filled in the interlayers. The IR spectrum further confirms the presence of BO3 groups. The calculated band structures and the density of states of Pb6AlB2O7F7 suggest that its indirect gap is 2.968 eV. The DSC analysis and X-ray diffraction technique prove that Pb6AlB2O7F7 is a congruent-melting compound.

关键词Pb6alb2o7f7 Borates Synthesis Crystal Structure
学科领域Chemistry
DOI10.1002/zaac.201200374
收录类别SCI
WOS记录号WOS:000310979300018
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2754
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China;Yili Normal Univ, Xinjiang Lab Phase Transit & Microstruct Condense, Yining 835000, Xinjiang, Peoples R China
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Dong Lingyun,Pan Shilie,Yang Zhihua,et al. Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2012,638(14):2280-2285.
APA Dong Lingyun.,Pan Shilie.,Yang Zhihua.,Zhao Wenwu.,Dong Xiaoyu.,...&Pan, SL.(2012).Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,638(14),2280-2285.
MLA Dong Lingyun,et al."Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 638.14(2012):2280-2285.
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