Dipotassium sodium niobium dioxide tetrafluoride, K2NaNbO2F4, crystal structure and characterization
Li Junjie; Pan Shilie; Tian Xuelin; Zhang Fangfang; Zhao Wenwu
2012
发表期刊JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
ISSN0022-3697
卷号73期号:1页码:136-138
摘要

The paper presents a new data on the crystal structure of K2NaNbO2F4. Single crystals of K2NaNbO2F4, were obtained from the system of KF-NaF-Nb2O5. The compound is cubic, space group Fm (3) over barm (No. 225), and the unit cell parameters are alpha=8.4726(4) angstrom, Z=4, Volume=608.21(5) angstrom(3). The structure was solved by the direct methods and refined to the reliability factors R-1 =0.0116 (wR(2)=0.0302). Its structure can be described as three-dimensional frameworks formed of (0 1 0) Na2Nb2O4F8infinity layers stacked along b axis. In the framework, niobium, oxygen, fluorine atoms form a rare NbO2F4(3-) anion group in an anhydrous solid state environment. The IR spectrum further confirmed the presence of NbO2 and NbF4 groups in the structure. The thermal analysis suggests that K2NaNbO2F4 is an incongruently melting compound.

关键词Crystal Growth X-ray Diffraction Chemical Synthesis Infrared Spectroscopy
学科领域Chemistry ; Physics
资助者Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001
DOI10.1016/j.jpcs.2011.10.024
收录类别SCI
资助者Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001 ; Chinese Academy of Sciences KJCX2-EW-H03-03 ; National Natural Science Foundation of China 50802110, 21001114 ; Xinjiang Uygur Autonomous Region of China 200816120 ; Scientific Research Program of Urumqi of China G09212001
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2729
专题新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Li Junjie,Pan Shilie,Tian Xuelin,et al. Dipotassium sodium niobium dioxide tetrafluoride, K2NaNbO2F4, crystal structure and characterization[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,2012,73(1):136-138.
APA Li Junjie,Pan Shilie,Tian Xuelin,Zhang Fangfang,&Zhao Wenwu.(2012).Dipotassium sodium niobium dioxide tetrafluoride, K2NaNbO2F4, crystal structure and characterization.JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,73(1),136-138.
MLA Li Junjie,et al."Dipotassium sodium niobium dioxide tetrafluoride, K2NaNbO2F4, crystal structure and characterization".JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 73.1(2012):136-138.
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