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学科主题: Chemistry ; Physics
题名: Pb8M(BO3)(6) (M = Zn, Cd): Two new isostructural lead borates compounds with two-dimensional (infinity)[Pb8B6O18](2-) layer structure
作者: Huang Zhenjun; Pan Shilie; Yang Zhihua; Yu Hongwei; Dong Xiaoyu; Zhao Wenwu; Dong Lingyun; Su Xiri
通讯作者: Pan, SL
关键词: Pb8Zn(BO3)(6) ; Pb8Cd(BO3)(6) ; Borate ; Synthesis ; Crystal structure
刊名: SOLID STATE SCIENCES
发表日期: 2013
DOI: 10.1016/j.solidstatesciences.2012.08.031
卷: 15, 期:1, 页:73-78
收录类别: SCI
资助者: National Natural Science Foundation of China U1129301, 51172277, 50802110, 21101167, 21101168, 11104344; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; Xinjiang Uygur Autonomous Region of China 201130111, 201116143
摘要: Single crystals of Pb8M(BO3)(6) (M=Zn, Cd) have been successfully synthesized by high temperature solution method and their structures are determined by single-crystal X-ray diffraction methods. The compounds crystallize in the trigonal space group R (3) over bar (No.148) with unit:cell parameters a = 9.505(6) angstrom, c = 18.162(9) angstrom, V = 1421(2) angstrom(3) for the Zn compound and a = 9.5584(16) angstrom, c = 18.670(3) angstrom, V = 1477.2(6) angstrom(3) for the Cd compound. Both of the materials represent a new two-dimensional (2D) (infinity)[Pb8B6O18](2-) layer, which is composed of BO3 and PbOx (x = 4,6) polyhedra. The layers are further bridged by the M2+ (Zn2+, Cd2+) ions, giving rise to a three-dimensional (3D) framework. Thermal analysis, IR spectroscopy, UV-Vis-NIR diffuse reflectance spectra, and band structure calculations are performed on the reported compounds.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2728
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Huang Zhenjun,Pan Shilie,Yang Zhihua,et al. Pb8M(BO3)(6) (M = Zn, Cd): Two new isostructural lead borates compounds with two-dimensional (infinity)[Pb8B6O18](2-) layer structure[J]. SOLID STATE SCIENCES,2013,15(1):73-78.
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文件名: Pb8M(BO3)(6) (M = Zn, Cd) Two new isostructural lead borates compounds with two-dimensional (infinity)[Pb8B6O18](2-) layer structure.pdf
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