New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)(2)]center dot 4H(2)O (A = K+, Rb+)
Fan Xiaoyun; Pan Shilie; Guo Jing; Hou Xueling; Han Jian; Zhang Fangfang; Li Feng; Poeppelmeier Kenneth R.
2013
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
ISSN2050-7488
Volume1Issue:35Pages:10389-10394
Abstract

Two new tartratoborate nonlinear optical materials, KSr[C4H2O6B(OH)(2)]center dot 4H(2)O (KSCB) and RbSr-[C4H2O6B(OH)(2)]center dot 4H(2)O (RSCB), have been prepared through slow evaporation at room temperature. Single-crystal X-ray diffraction data reveal that KSCB crystallizes in the triclinic system, space group P1 (no. 1). It consists of KO8 polyhedra, SrO9 polyhedra, BO4 tetrahedra, tartrate molecules and H2O molecules. The isolated tartratoborate anions are connected to form a three-dimensional network structure by sharing oxygen atoms with K+ and Sr2+. The structural data show that KSCB and RSCB are isostructural and noncentrosymmetric. KSCB and RSCB produce second-harmonic generation intensities of 1.5 x KH2PO4 and 1.7 x KH2PO4, respectively, and they are both type I phase-matchable. The UV-Vis diffuse reflectance spectra of these compounds indicate that they are both transparent from 250 to 850 nm. Related infrared spectra and thermal analyses were also performed.

Subject AreaChemistry ; Energy & Fuels ; Materials Science
DOI10.1039/c3ta10474e
Indexed BySCI
WOS IDWOS:000323132700042
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2706
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
Recommended Citation
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Fan Xiaoyun,Pan Shilie,Guo Jing,et al. New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)(2)]center dot 4H(2)O (A = K+, Rb+)[J]. JOURNAL OF MATERIALS CHEMISTRY A,2013,1(35):10389-10394.
APA Fan Xiaoyun.,Pan Shilie.,Guo Jing.,Hou Xueling.,Han Jian.,...&Poeppelmeier Kenneth R..(2013).New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)(2)]center dot 4H(2)O (A = K+, Rb+).JOURNAL OF MATERIALS CHEMISTRY A,1(35),10389-10394.
MLA Fan Xiaoyun,et al."New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)(2)]center dot 4H(2)O (A = K+, Rb+)".JOURNAL OF MATERIALS CHEMISTRY A 1.35(2013):10389-10394.
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