中国科学院新疆理化技术研究所机构知识库
Advanced  
XJIPC OpenIR  > 新疆维吾尔自治区电子信息材料与器件重点实验室  > 期刊论文
学科主题: Chemistry ; Energy & Fuels ; Materials Science
题名: New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)(2)]center dot 4H(2)O (A = K+, Rb+)
作者: Fan Xiaoyun; Pan Shilie; Guo Jing; Hou Xueling; Han Jian; Zhang Fangfang; Li Feng; Poeppelmeier Kenneth R.
刊名: JOURNAL OF MATERIALS CHEMISTRY A
发表日期: 2013
DOI: 10.1039/c3ta10474e
卷: 1, 期:35, 页:10389-10394
收录类别: SCI
资助者: National Natural Science Foundation of China 20111104, U1129301, 51172277, 50802110, 21101168, 11104344; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; "One Hundred Talents Project Foundation Program" of Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 201116143; National Science Foundation Solid State and Materials Chemistry Award DMR-1005827
摘要:

Two new tartratoborate nonlinear optical materials, KSr[C4H2O6B(OH)(2)]center dot 4H(2)O (KSCB) and RbSr-[C4H2O6B(OH)(2)]center dot 4H(2)O (RSCB), have been prepared through slow evaporation at room temperature. Single-crystal X-ray diffraction data reveal that KSCB crystallizes in the triclinic system, space group P1 (no. 1). It consists of KO8 polyhedra, SrO9 polyhedra, BO4 tetrahedra, tartrate molecules and H2O molecules. The isolated tartratoborate anions are connected to form a three-dimensional network structure by sharing oxygen atoms with K+ and Sr2+. The structural data show that KSCB and RSCB are isostructural and noncentrosymmetric. KSCB and RSCB produce second-harmonic generation intensities of 1.5 x KH2PO4 and 1.7 x KH2PO4, respectively, and they are both type I phase-matchable. The UV-Vis diffuse reflectance spectra of these compounds indicate that they are both transparent from 250 to 850 nm. Related infrared spectra and thermal analyses were also performed.

Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2706
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

Files in This Item:
File Name/ File Size Content Type Version Access License
New tartratoborates synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)(2)]center dot 4H(2)O (A = K+, Rb+).pdf(394KB)期刊论文作者接受稿开放获取View 联系获取全文

作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

Recommended Citation:
Fan Xiaoyun,Pan Shilie,Guo Jing,et al. New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)(2)]center dot 4H(2)O (A = K+, Rb+)[J]. JOURNAL OF MATERIALS CHEMISTRY A,2013,1(35):10389-10394.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Fan Xiaoyun]'s Articles
[Pan Shilie]'s Articles
[Guo Jing]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Fan Xiaoyun]‘s Articles
[Pan Shilie]‘s Articles
[Guo Jing]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: New tartratoborates synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)(2)]center dot 4H(2)O (A = K+, Rb+).pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace