synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: rbpbbp2o8
Wang Ying; Pan Shilie; Zhang Min; Han Shujuan; Su Xin; Dong Lingyun
2013
Source PublicationCRYSTENGCOMM
ISSN1466-8033
Volume15Issue:24Pages:4956-4962
Abstract

A new noncentrosymmetric borophosphate, RbPbBP2O8, has been synthesized and its high quality single crystal with dimensions up to 23 mm x 18 mm x 7 mm was successfully grown by the Kyropoulos method for the first time. It crystallizes in the tetragonal system, space group I42d with cell parameters a = 7.213(3) angstrom, c = 13.987(10) angstrom, Z = 4, V = 727.8(6) angstrom(3). The structure analysis reveals that RbPbBP2O8 features a three-dimensional framework composed of BO4 and PO4 tetrahedra interconnected by MO8 (M = Rb/Pb) distorted polyhedra. The powder second harmonic generation effect of RbPbBP2O8 is similar to that of KH2PO4. Thermal analysis and transmittance spectroscopy were also performed on the reported crystal.

Subject AreaChemistry ; Crystallography
DOI10.1039/c3ce40394g
Indexed BySCI
WOS IDWOS:000319512000022
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2698
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang Ying,Pan Shilie,Zhang Min,et al. synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: rbpbbp2o8[J]. CRYSTENGCOMM,2013,15(24):4956-4962.
APA Wang Ying,Pan Shilie,Zhang Min,Han Shujuan,Su Xin,&Dong Lingyun.(2013).synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: rbpbbp2o8.CRYSTENGCOMM,15(24),4956-4962.
MLA Wang Ying,et al."synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: rbpbbp2o8".CRYSTENGCOMM 15.24(2013):4956-4962.
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