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学科主题: Chemistry ; Crystallography
题名: Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units
作者: Zhou Lin; Pan Shilie; Dong Xiaoyu; Yu Hongwei; Wu Hongping; Zhang Fangfang; Zhou Zhongxiang
刊名: CRYSTENGCOMM
发表日期: 2013
DOI: 10.1039/c3ce26587k
卷: 15, 期:17, 页:3412-3416
收录类别: SCI
资助者: National Natural Science Foundation of China U1129301, 51172277, 21201176, 50802110, 21101167, 21101168, 11104344; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; "One Hundred Talents Project Foundation Program" of Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 201116143
摘要: A new noncentrosymmetric compound, Na2Cd7B8O20, has been synthesized by solid-state reaction for the first time. The crystal structure has been determined from single crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Fdd2 with a = 51.5597(7) angstrom, b = 58.6920(8) angstrom and c = 3.381 angstrom. The crystal structure is composed of CdOn (n = 6, 7), Na-CdOn (n = 5, 6) NaOn (n = 4, 6) polyhedra, B3O7 and BO3 units. The B3O7 unit is built up of three BO3 groups via corner-sharing, rarely found in borate compounds. The IR spectrum, the optical diffuse reflectance spectrum and nonlinear optical properties of Na2Cd7B8O20 are reported.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2694
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Zhou Lin,Pan Shilie,Dong Xiaoyu,et al. Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units[J]. CRYSTENGCOMM,2013,15(17):3412-3416.
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文件名: Na2Cd7B8O20 a new noncentrosymmetric compound with special [B3O7] units.pdf
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