Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units
Zhou Lin; Pan Shilie; Dong Xiaoyu; Yu Hongwei; Wu Hongping; Zhang Fangfang; Zhou Zhongxiang
2013
Source PublicationCRYSTENGCOMM
ISSN1466-8033
Volume15Issue:17Pages:3412-3416
Abstract

A new noncentrosymmetric compound, Na2Cd7B8O20, has been synthesized by solid-state reaction for the first time. The crystal structure has been determined from single crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Fdd2 with a = 51.5597(7) angstrom, b = 58.6920(8) angstrom and c = 3.381 angstrom. The crystal structure is composed of CdOn (n = 6, 7), Na-CdOn (n = 5, 6) NaOn (n = 4, 6) polyhedra, [B3O7] and [BO3] units. The [B3O7] unit is built up of three [BO3] groups via corner-sharing, rarely found in borate compounds. The IR spectrum, the optical diffuse reflectance spectrum and nonlinear optical properties of Na2Cd7B8O20 are reported.

Subject AreaChemistry ; Crystallography
DOI10.1039/c3ce26587k
Indexed BySCI
WOS IDWOS:000316962300026
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2694
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhou Lin,Pan Shilie,Dong Xiaoyu,et al. Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units[J]. CRYSTENGCOMM,2013,15(17):3412-3416.
APA Zhou Lin.,Pan Shilie.,Dong Xiaoyu.,Yu Hongwei.,Wu Hongping.,...&Zhou Zhongxiang.(2013).Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units.CRYSTENGCOMM,15(17),3412-3416.
MLA Zhou Lin,et al."Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units".CRYSTENGCOMM 15.17(2013):3412-3416.
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