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学科主题: Chemistry
题名: effects of alkali halide salts on hydrocarboxylation of styrene catalyzed by water-soluble palladium phosphine complexes
作者: He Zhenhong; Hou Zhenshan; Luo Yanping; Zhou Liang; Liu Yuanfeng; Eli Wumanjiang
关键词: Aqueous two-phase system ; Hydrocarboxylation ; Palladium-phosphine complexes ; Alkali metal halide
刊名: CATALYSIS LETTERS
发表日期: 2013
DOI: 10.1007/s10562-013-0961-2
卷: 143, 期:3, 页:289-297
收录类别: SCI
资助者: National Natural Science Foundation of China U1179302; Chinese Academy of Sciences
摘要: Hydrocarboxylation of styrene catalyzed by water-soluble Pd-TPPTS complexes was investigated. The reaction conditions, including reaction pressure, temperature, time and etc. have a significant influence on the catalytic performance. It was found that the yield of total acids and the selectivity towards 3-phenylpropionic acid were enhanced by adding a suitable amount of alkali metal halide salts. In addition, the reaction mechanism and the role of alkali metal halide salts in the reaction were discussed on the basis of the characterization of H-1 NMR and P-31 NMR.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2674
Appears in Collections:新疆维吾尔自治区精细化工工程技术研究中心_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;E China Univ Sci & Technol, Key Lab Adv Mat, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

Recommended Citation:
He Zhenhong,Hou Zhenshan,Luo Yanping,et al. effects of alkali halide salts on hydrocarboxylation of styrene catalyzed by water-soluble palladium phosphine complexes[J]. CATALYSIS LETTERS,2013,143(3):289-297.
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文件名: effects of alkali halide salts on hydrocarboxylation of styrene catalyzed by water-soluble palladium phosphine complexes.pdf
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