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学科主题: Chemistry
题名: synthesis, structure characterization, and optical properties of the aluminosilicate li2na3alsi2o8
作者: Han Shujuan; Pan Shilie; Yang Zhihua; Wang Ying; Zhang Bingbing; Zhang Min; Huang Zhenjun; Dong Lingyun; Yu Hongwei
通讯作者: Pan, SL
关键词: Crystal structure ; Diffuse reflectance spectroscopy ; Lithium ; Aluminosilicates ; Silicates
刊名: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
发表日期: 2013
DOI: 10.1002/zaac.201200521
卷: 639, 期:5, 页:779-783
收录类别: SCI
资助者: Western Light of Chinese Academy of Sciences XBBS201220; National Key Basic Research Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143
摘要: The aluminosilicate Li2Na3AlSi2O8 was crystallized from the Li2CO3H3BO3 flux system. It crystallizes in the orthorhombic space group Cmca, with cell dimensions a = 14.1045 (19) angstrom, b = 14.7054 (19) angstrom, c = 7.0635 (9) angstrom, and Z = 8. The crystal structure consists of a two-dimensional infinite layer, which is composed of Al2Si2O12 groups and SiO4 tetrahedra. The lithium and sodium atoms filling in the interlayer and intralayer link the layers together and balance the charge. IR spectroscopy and BVS calculations were used to verify the validity of the structure. The calculated band structures and the density of states of Li2Na3AlSi2O8 suggest that its direct gap is 4.28 eV.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2669
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Han Shujuan,Pan Shilie,Yang Zhihua,et al. synthesis, structure characterization, and optical properties of the aluminosilicate li2na3alsi2o8[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2013,639(5):779-783.
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文件名: Synthesis, Structure Characterization, and Optical Properties of the Aluminosilicate Li2Na3AlSi2O8.pdf
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