synthesis, structure characterization, and optical properties of the aluminosilicate li2na3alsi2o8
Han Shujuan; Pan Shilie; Yang Zhihua; Wang Ying; Zhang Bingbing; Zhang Min; Huang Zhenjun; Dong Lingyun; Yu Hongwei
2013
发表期刊ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
卷号639期号:5页码:779-783
摘要

The aluminosilicate Li2Na3AlSi2O8 was crystallized from the Li2CO3H3BO3 flux system. It crystallizes in the orthorhombic space group Cmca, with cell dimensions a = 14.1045 (19) angstrom, b = 14.7054 (19) angstrom, c = 7.0635 (9) angstrom, and Z = 8. The crystal structure consists of a two-dimensional infinite layer, which is composed of [Al2Si2O12] groups and [SiO4] tetrahedra. The lithium and sodium atoms filling in the interlayer and intralayer link the layers together and balance the charge. IR spectroscopy and BVS calculations were used to verify the validity of the structure. The calculated band structures and the density of states of Li2Na3AlSi2O8 suggest that its direct gap is 4.28 eV.

关键词Crystal Structure Diffuse Reflectance Spectroscopy Lithium Aluminosilicates Silicates
学科领域Chemistry
DOI10.1002/zaac.201200521
收录类别SCI
WOS记录号WOS:000318099100019
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2669
专题新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Han Shujuan,Pan Shilie,Yang Zhihua,et al. synthesis, structure characterization, and optical properties of the aluminosilicate li2na3alsi2o8[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2013,639(5):779-783.
APA Han Shujuan.,Pan Shilie.,Yang Zhihua.,Wang Ying.,Zhang Bingbing.,...&Yu Hongwei.(2013).synthesis, structure characterization, and optical properties of the aluminosilicate li2na3alsi2o8.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,639(5),779-783.
MLA Han Shujuan,et al."synthesis, structure characterization, and optical properties of the aluminosilicate li2na3alsi2o8".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 639.5(2013):779-783.
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