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Effect of doubly organo-modified vermiculite on the properties of vermiculite/polystyrene nanocomposites
Wang Lan; Wang Xu; Chen Zhaoyang; Ma Pengcheng
2013
Source PublicationAPPLIED CLAY SCIENCE
ISSN0169-1317
Volume75-76Issue:5Pages:74-81
AbstractVermiculite (Verm)/polystyrene (PS) nanocomposites were prepared by dispersing a doubly organo-modified Verm (DOVerm) in PS via in situ polymerization (DOVerm/PS 1/99, 3/97, 5/95, and 7/93 mass/mass ratios). The morphology of Verm/PS nanocomposites evolved three stages as the content of DOVerm decreased in the nanocomposites: intercalation at high filler content, intermediate state of intercalation to exfoliation, and exfoliation of Verm in PS matrix with a low filler content. The morphological changes of Verm/PS nanocomposites were confirmed by the X-ray diffraction (XRD) patterns and the transmission electron microscopy (TEM) images. Compared with the pure PS, the nanocomposites filled with Verm showed significant enhancements on thermal stability and dynamic mechanical properties. Interestingly, the nanocomposites filled with 1 and 7 mass% of DOVerm exhibited more pronounced effects of Verm on the properties. It was proved that the double organo-modification clearly enhanced the ultimate properties of the Verm/PS nanocomposites. (C) 2013 Elsevier B.V. All rights reserved.
KeywordVermiculite Polystyrene Clay Mineral Polymer Nanocomposite (Cpn) Thermal Stability Dynamic Mechanical Properties
Subject AreaChemistry ; Materials Science ; Mineralogy
DOI10.1016/j.clay.2013.03.005
Indexed BySCI
WOS IDWOS:000318835800010
Citation statistics
Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2665
Collection环境科学与技术研究室
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Urumqi 830011, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Green Chem & Organ Synth, Urumqi 830011, Peoples R China;Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
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Wang Lan,Wang Xu,Chen Zhaoyang,et al. Effect of doubly organo-modified vermiculite on the properties of vermiculite/polystyrene nanocomposites[J]. APPLIED CLAY SCIENCE,2013,75-76(5):74-81.
APA Wang Lan,Wang Xu,Chen Zhaoyang,&Ma Pengcheng.(2013).Effect of doubly organo-modified vermiculite on the properties of vermiculite/polystyrene nanocomposites.APPLIED CLAY SCIENCE,75-76(5),74-81.
MLA Wang Lan,et al."Effect of doubly organo-modified vermiculite on the properties of vermiculite/polystyrene nanocomposites".APPLIED CLAY SCIENCE 75-76.5(2013):74-81.
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