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学科主题: Chemistry
题名:
New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles
作者: Yu Hongwei; Wu Hongping; Pan ShiLie(潘世烈); Wang Ying; Yang Zhihua; Su Xin
通讯作者: Pan, SL
刊名: INORGANIC CHEMISTRY
发表日期: 2013
DOI: 10.1021/ic4002779
卷: 52, 期:9, 页:5359-5365
收录类别: SCI
英文摘要:

Introduction of the coplanar BO3 triangles in the alkali metal and alkaline-earth metal mixed fluoborate generates a new UV nonlinear optical material [Li3Ca9(BO3)(7)]center dot 2[LiF] (LCBF), which possesses a moderate SHG response as large as that of the KDP and a wide transparent region with a UV cutoff edge at 230 nm. The first-principle theoretical calculation suggests that LCBF has a relatively large birefringence (0.07; 532 nm). These properties make it a potential UV nonlinear optical material. And interestingly, LCBF is a salt-inclusion borate with the Li-F chains residing in the one-dimensional open framework, which caters to the development of the salt-inclusion compound in borate.

WOS记录号: WOS:000318669400073
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2661
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF] A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles.pdf(1525KB)期刊论文作者接受稿开放获取View 联系获取全文

作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Yu Hongwei,Wu Hongping,Pan Shilie,et al. New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles[J]. INORGANIC CHEMISTRY,2013-01-01,52(9):5359-5365.
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文件名: New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF] A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles.pdf
格式: Adobe PDF
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