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学科主题: Chemistry
题名: new salt-inclusion borate, li3ca9(bo3)(7)center dot 2lif: a promising uv nlo material with the coplanar and high density bo3 triangles
作者: Yu Hongwei; Wu Hongping; Pan Shilie; Wang Ying; Yang Zhihua; Su Xin
通讯作者: Pan, SL
刊名: INORGANIC CHEMISTRY
发表日期: 2013
DOI: 10.1021/ic4002779
卷: 52, 期:9, 页:5359-5365
收录类别: SCI
资助者: National Key Basic Research Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344, 21201176; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; "One Hundred Talents Project Foundation Program" of Chinese Academy of Sciences; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 201116143; Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period 201130111
摘要: Introduction of the coplanar BO3 triangles in the alkali metal and alkaline-earth metal mixed fluoborate generates a new UV nonlinear optical material Li3Ca9(BO3)(7)center dot 2LiF (LCBF), which possesses a moderate SHG response as large as that of the KDP and a wide transparent region with a UV cutoff edge at 230 nm. The first-principle theoretical calculation suggests that LCBF has a relatively large birefringence (0.07; 532 nm). These properties make it a potential UV nonlinear optical material. And interestingly, LCBF is a salt-inclusion borate with the Li-F chains residing in the one-dimensional open framework, which caters to the development of the salt-inclusion compound in borate.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2661
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Yu Hongwei,Wu Hongping,Pan Shilie,et al. new salt-inclusion borate, li3ca9(bo3)(7)center dot 2lif: a promising uv nlo material with the coplanar and high density bo3 triangles[J]. INORGANIC CHEMISTRY,2013,52(9):5359-5365.
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文件名: New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF] A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles.pdf
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