Electrochemical layer-by-layer fabrication of a novel three-dimensional Pt/graphene/carbon fiber electrode and its improved catalytic performance for methanol electrooxidation in alkaline medium
Yao Zhangquan; Yue Ruirui; Zhai Chunyang; Jiang Fengxing; Wang Huiwen; Du Yukou; Wang Chuangyi; Yang Ping
2013
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN0360-3199
Volume38Issue:15Pages:6368-6376
Abstract

Here, we report a novel method for assembling reduced graphene oxide (RGO) and Pt nanoparticles on a carbon fiber (CF) electrode successively to form a stable Pt nanoparticle-RGO-Pt nanoparticle-RGO/CF multiple junction for electrocatalysis application. As the SEM imaging exhibited, Pt nanoparticles are uniformly deposited on the surface of each RGO sheet, performing an alternative covering structure of RGO and Pt nanoparticle multi-layer on the CF electrode. Thus, a novel three-dimensional (3D) multi-layered Pt/RGO modified CF electrode (N-Pt/RGO/CF) is obtained. Experimental results demonstrate that the prepared N-Pt/RGO/CF electrode shows good electrochemical properties and enhanced electrocatalytic activity toward methanol electrooxidation in alkaline medium as compared with the Pt/RGO/CF electrode without layer-by-layer structure or the Pt/CF electrode without RGO. It is due to the unique 3D pore structure of N-Pt/RGO/CF and the good electron transport property of RGO in the composite electrode.

KeywordLayer-by-layer Structure Reduced Graphene Oxide Electrocatalysis Electro-deposition Methanol Electrooxidation
Subject AreaChemistry ; Electrochemistry ; Energy & Fuels
DOI10.1016/j.ijhydene.2013.02.140
Indexed BySCI
WOS IDWOS:000319233000010
Citation statistics
Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2659
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
AffiliationSoochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China;Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Yao Zhangquan,Yue Ruirui,Zhai Chunyang,et al. Electrochemical layer-by-layer fabrication of a novel three-dimensional Pt/graphene/carbon fiber electrode and its improved catalytic performance for methanol electrooxidation in alkaline medium[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2013,38(15):6368-6376.
APA Yao Zhangquan.,Yue Ruirui.,Zhai Chunyang.,Jiang Fengxing.,Wang Huiwen.,...&Yang Ping.(2013).Electrochemical layer-by-layer fabrication of a novel three-dimensional Pt/graphene/carbon fiber electrode and its improved catalytic performance for methanol electrooxidation in alkaline medium.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,38(15),6368-6376.
MLA Yao Zhangquan,et al."Electrochemical layer-by-layer fabrication of a novel three-dimensional Pt/graphene/carbon fiber electrode and its improved catalytic performance for methanol electrooxidation in alkaline medium".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 38.15(2013):6368-6376.
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