synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10
Zhou Lin; Pan Shilie; Su Xin; Yu Hongwei; Yang Zhihua; Zhang Fangfang; Zhou Zhongxiang; Han Shujuan
2013
Source PublicationJOURNAL OF MOLECULAR STRUCTURE
ISSN0022-2860
Volume1040Issue:5Pages:180-183
Abstract

A novel lithium dilead pentaborate compound, LiPb2B5O10, is synthesized by the high temperature solution method for the first time. It crystallizes in the monoclinic space group P2(1)/m with lattice constants a = 4.4023(10) angstrom, b = 14.037(3) angstrom, c = 6.8846(16) angstrom, beta = 107.408(2)degrees and Z = 2. The structure consists of B5O (10) units, Liat and PbO7 polyhedra. The B5O10 unit is composed of three BO3 triangles and two Bat tetrahedra. The IR spectrum further confirms the presence of both BO3 and BO4 groups. The calculated band gap via ab initio methods is about 3.433 eV, which is consistent with the experimental result obtained from UV-vis-NIR diffuse reflectance spectrum.

KeywordLipb2b5o10 Borate Synthesis Crystal Structure
Subject AreaChemistry
DOI10.1016/j.molstruc.2013.03.007
Indexed BySCI
WOS IDWOS:000318961000024
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2658
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
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Zhou Lin,Pan Shilie,Su Xin,et al. synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10[J]. JOURNAL OF MOLECULAR STRUCTURE,2013,1040(5):180-183.
APA Zhou Lin.,Pan Shilie.,Su Xin.,Yu Hongwei.,Yang Zhihua.,...&Han Shujuan.(2013).synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10.JOURNAL OF MOLECULAR STRUCTURE,1040(5),180-183.
MLA Zhou Lin,et al."synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10".JOURNAL OF MOLECULAR STRUCTURE 1040.5(2013):180-183.
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