synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10
Zhou Lin; Pan Shilie; Su Xin; Yu Hongwei; Yang Zhihua; Zhang Fangfang; Zhou Zhongxiang; Han Shujuan; Pan, SL
2013
发表期刊JOURNAL OF MOLECULAR STRUCTURE
ISSN0022-2860
卷号1040期号:5页码:180-183
摘要

A novel lithium dilead pentaborate compound, LiPb2B5O10, is synthesized by the high temperature solution method for the first time. It crystallizes in the monoclinic space group P2(1)/m with lattice constants a = 4.4023(10) angstrom, b = 14.037(3) angstrom, c = 6.8846(16) angstrom, beta = 107.408(2)degrees and Z = 2. The structure consists of B5O (10) units, Liat and PbO7 polyhedra. The B5O10 unit is composed of three BO3 triangles and two Bat tetrahedra. The IR spectrum further confirms the presence of both BO3 and BO4 groups. The calculated band gap via ab initio methods is about 3.433 eV, which is consistent with the experimental result obtained from UV-vis-NIR diffuse reflectance spectrum.

关键词Lipb2b5o10 Borate Synthesis Crystal Structure
学科领域Chemistry
DOI10.1016/j.molstruc.2013.03.007
收录类别SCI
WOS记录号WOS:000318961000024
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2658
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Zhou Lin,Pan Shilie,Su Xin,et al. synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10[J]. JOURNAL OF MOLECULAR STRUCTURE,2013,1040(5):180-183.
APA Zhou Lin.,Pan Shilie.,Su Xin.,Yu Hongwei.,Yang Zhihua.,...&Pan, SL.(2013).synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10.JOURNAL OF MOLECULAR STRUCTURE,1040(5),180-183.
MLA Zhou Lin,et al."synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, lipb2b5o10".JOURNAL OF MOLECULAR STRUCTURE 1040.5(2013):180-183.
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