synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties
Li Hongyi; Zhao Yi; Pan Shilie; Wu Hongping; Yu Hongwei; Zhang Fangfang; Yang Zhihua; Poeppelmeier Kenneth R.
2013
Source PublicationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
Issue18Pages:3185-3190
Abstract

For the first time, single crystals of KPbBP2O8 with sizes up to 18x13x6 mm have been grown from a stoichiometric mixture of its components by the top seed growth method. The crystal structure was determined from single-crystal X-ray data: tetragonal, space group I$\bar {4}$2d, a = 7.1464(7) angstrom, c = 13.8917(16) angstrom, Z = 4. It exhibits an isolated [BP2O8]3- unit that is built from nearly ideal tetrahedral BO4 and PO4 groups, which are connected to each other alternatively by corner-sharing O atoms to make a 12-membered ring. Transmission spectroscopy illustrates that the UV cutoff edge is at approximately 235 nm. Furthermore, IR spectroscopy, thermal analysis, and second-harmonic generation (SHG) measurements were also performed on the reported material.

KeywordBorates Phosphates Lead Nonlinear Optics
Subject AreaChemistry
DOI10.1002/ejic.201300009
Indexed BySCI
WOS IDWOS:000320275000009
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2655
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
Recommended Citation
GB/T 7714
Li Hongyi,Zhao Yi,Pan Shilie,et al. synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013(18):3185-3190.
APA Li Hongyi.,Zhao Yi.,Pan Shilie.,Wu Hongping.,Yu Hongwei.,...&Poeppelmeier Kenneth R..(2013).synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(18),3185-3190.
MLA Li Hongyi,et al."synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .18(2013):3185-3190.
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