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学科主题: Chemistry
题名: synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties
作者: Li Hongyi; Zhao Yi; Pan Shilie; Wu Hongping; Yu Hongwei; Zhang Fangfang; Yang Zhihua; Poeppelmeier Kenneth R.
通讯作者: Pan, SL
关键词: Borates ; Phosphates ; Lead ; Nonlinear optics
刊名: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
发表日期: 2013
DOI: 10.1002/ejic.201300009
期: 18, 页:3185-3190
收录类别: SCI
资助者: 973 Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of CAS KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of CAS; Funds for Creative Cross & Cooperation Teams of CAS; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research & Development Program of Xinjiang Uygur Autonomous Region of China 201116143; Science and Technology Project of Urumqi G121130002; National Science Foundation Solid State Chemistry Award DMR-1005827
摘要: For the first time, single crystals of KPbBP2O8 with sizes up to 18x13x6 mm have been grown from a stoichiometric mixture of its components by the top seed growth method. The crystal structure was determined from single-crystal X-ray data: tetragonal, space group I$\bar {4}$2d, a = 7.1464(7) angstrom, c = 13.8917(16) angstrom, Z = 4. It exhibits an isolated [BP2O8]3- unit that is built from nearly ideal tetrahedral BO4 and PO4 groups, which are connected to each other alternatively by corner-sharing O atoms to make a 12-membered ring. Transmission spectroscopy illustrates that the UV cutoff edge is at approximately 235 nm. Furthermore, IR spectroscopy, thermal analysis, and second-harmonic generation (SHG) measurements were also performed on the reported material.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2655
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

Recommended Citation:
Li Hongyi,Zhao Yi,Pan Shilie,et al. synthesis and structure of kpbbp2o8-a congruent melting borophosphate with nonlinear optical properties[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013(18):3185-3190.
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文件名: Synthesis and Structure of KPbBP2O8-A Congruent Melting Borophosphate with Nonlinear Optical Properties.pdf
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