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学科主题: Chemistry
题名: Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation
作者: Wang Hong-Tu; Lu Chong-Dao
通讯作者: Lu, CD
关键词: Dirhodium(II) ; Catalysis ; Oxidation ; Cycloaddition ; Pyrrolo2,1-aisoquinolines
刊名: TETRAHEDRON LETTERS
发表日期: 2013
DOI: 10.1016/j.tetlet.2013.04.004
卷: 54, 期:23, 页:3015-3018
收录类别: SCI
资助者: National Natural Science Foundation of China 21172251; Chinese Academy of Sciences
摘要: Azomethine ylides have been efficiently generated via Rh-2(cap)(4)-catalyzed oxidation of tetrahydroisoquinoline derivatives in the presence of base. The ylides are trapped in situ via 3+2 cycloaddition with dipolarophiles and subjected to oxidative aromatization facilitated by N-bromosuccinimide to provide 3,4-dihydropyrrolo2,1-aisoquinoline derivatives in moderate to excellent yields.
英文摘要: A
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2653
Appears in Collections:资源化学研究室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Wang Hong-Tu,Lu Chong-Dao. Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation[J]. TETRAHEDRON LETTERS,2013,54(23):3015-3018.
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文件名: Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh2(cap)4-catalyzed oxidation.pdf
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