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Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation
Wang Hong-Tu; Lu Chong-Dao; Lu, CD
2013
发表期刊TETRAHEDRON LETTERS
ISSN0040-4039
卷号54期号:23页码:3015-3018
摘要Azomethine ylides have been efficiently generated via Rh-2(cap)(4)-catalyzed oxidation of tetrahydroisoquinoline derivatives in the presence of base. The ylides are trapped in situ via 3+2 cycloaddition with dipolarophiles and subjected to oxidative aromatization facilitated by N-bromosuccinimide to provide 3,4-dihydropyrrolo2,1-aisoquinoline derivatives in moderate to excellent yields.
关键词Dirhodium(Ii) Catalysis Oxidation Cycloaddition Pyrrolo2 1-aisoquinolines
学科领域Chemistry
DOI10.1016/j.tetlet.2013.04.004
收录类别SCI
WOS记录号WOS:000318832200029
引用统计
被引频次:17[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2653
专题资源化学研究室
通讯作者Lu, CD
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Wang Hong-Tu,Lu Chong-Dao,Lu, CD. Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation[J]. TETRAHEDRON LETTERS,2013,54(23):3015-3018.
APA Wang Hong-Tu,Lu Chong-Dao,&Lu, CD.(2013).Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation.TETRAHEDRON LETTERS,54(23),3015-3018.
MLA Wang Hong-Tu,et al."Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation".TETRAHEDRON LETTERS 54.23(2013):3015-3018.
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