| Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation | |
| Wang Hong-Tu; Lu Chong-Dao; Lu, CD | |
| 2013 | |
| 发表期刊 | TETRAHEDRON LETTERS
 |
| ISSN | 0040-4039 |
| 卷号 | 54期号:23页码:3015-3018 |
| 摘要 | Azomethine ylides have been efficiently generated via Rh-2(cap)(4)-catalyzed oxidation of tetrahydroisoquinoline derivatives in the presence of base. The ylides are trapped in situ via 3+2 cycloaddition with dipolarophiles and subjected to oxidative aromatization facilitated by N-bromosuccinimide to provide 3,4-dihydropyrrolo2,1-aisoquinoline derivatives in moderate to excellent yields. |
| 关键词 | Dirhodium(Ii) Catalysis Oxidation Cycloaddition Pyrrolo2 1-aisoquinolines |
| 学科领域 | Chemistry |
| DOI | 10.1016/j.tetlet.2013.04.004 |
| 收录类别 | SCI |
| WOS记录号 | WOS:000318832200029 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.xjipc.cas.cn/handle/365002/2653 |
| 专题 | 资源化学研究室 |
| 通讯作者 | Lu, CD |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Hong-Tu,Lu Chong-Dao,Lu, CD. Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation[J]. TETRAHEDRON LETTERS,2013,54(23):3015-3018. |
| APA | Wang Hong-Tu,Lu Chong-Dao,&Lu, CD.(2013).Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation.TETRAHEDRON LETTERS,54(23),3015-3018. |
| MLA | Wang Hong-Tu,et al."Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation".TETRAHEDRON LETTERS 54.23(2013):3015-3018. |
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| Synthesis of 3,4-dih（2926KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 请求全文 | |
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