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Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation
Wang Hong-Tu; Lu Chong-Dao; Lu, CD
2013
Source PublicationTETRAHEDRON LETTERS
ISSN0040-4039
Volume54Issue:23Pages:3015-3018
AbstractAzomethine ylides have been efficiently generated via Rh-2(cap)(4)-catalyzed oxidation of tetrahydroisoquinoline derivatives in the presence of base. The ylides are trapped in situ via 3+2 cycloaddition with dipolarophiles and subjected to oxidative aromatization facilitated by N-bromosuccinimide to provide 3,4-dihydropyrrolo2,1-aisoquinoline derivatives in moderate to excellent yields.
KeywordDirhodium(Ii) Catalysis Oxidation Cycloaddition Pyrrolo2 1-aisoquinolines
Subject AreaChemistry
DOI10.1016/j.tetlet.2013.04.004
Indexed BySCI
WOS IDWOS:000318832200029
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2653
Collection资源化学研究室
Corresponding AuthorLu, CD
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang Hong-Tu,Lu Chong-Dao,Lu, CD. Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation[J]. TETRAHEDRON LETTERS,2013,54(23):3015-3018.
APA Wang Hong-Tu,Lu Chong-Dao,&Lu, CD.(2013).Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation.TETRAHEDRON LETTERS,54(23),3015-3018.
MLA Wang Hong-Tu,et al."Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation".TETRAHEDRON LETTERS 54.23(2013):3015-3018.
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