Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)
Dong Lingyun; Pan Shilie; Wu Hongping; Su Xin; Yu Hongwei; Wang Ying; Chen Zhaohui; Huang Zhenjun; Yang Zhihua
2013
Source PublicationJOURNAL OF SOLID STATE CHEMISTRY
ISSN0022-4596
Volume204Issue:8Pages:64-69
Abstract

A series of lead-containing halogen oxyborates, Pb6B3O10X (X=F, Cl, Br), have been grown by high-temperature solution method and their crystal structures were determined by single-crystal X-ray diffraction. They are isostructural and crystallize in the space group Pbcm of the orthorhombic crystal system. The crystal structures are dominated by one-dimensional (infinity)(Pb4O)(BO3)(3)"Zig-Zag"-chains, while the remaining Pb atoms and X (X=F, Cl, Br) atoms are filled to balance the charge. Compared with the previously reported compound Pb4O(BO3)(2) (the molecular formula Pb4O(BO3)(2) can be regarded as Pb6B3O10.5) with the space group Aba2, the structures of Pb6B3O10X (X=F, Cl, Br) are completely different from that of Pb4O(BO3)(2). IR spectroscopy, UV vis-NIR diffuse reflectance spectroscopy, thermal analysis, and theoretical calculations were also performed on the reported materials.

KeywordOxyborates Pb6b3o10x (X=f Crystal Structures Cl Syntheses Br) Optical Properties
Subject AreaChemistry
DOI10.1016/j.jssc.2013.05.016
Indexed BySCI
WOS IDWOS:000322932600011
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2642
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Dong Lingyun,Pan Shilie,Wu Hongping,et al. Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)[J]. JOURNAL OF SOLID STATE CHEMISTRY,2013,204(8):64-69.
APA Dong Lingyun.,Pan Shilie.,Wu Hongping.,Su Xin.,Yu Hongwei.,...&Yang Zhihua.(2013).Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br).JOURNAL OF SOLID STATE CHEMISTRY,204(8),64-69.
MLA Dong Lingyun,et al."Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)".JOURNAL OF SOLID STATE CHEMISTRY 204.8(2013):64-69.
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