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学科主题: Chemistry
题名: Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)
作者: Dong Lingyun; Pan Shilie; Wu Hongping; Su Xin; Yu Hongwei; Wang Ying; Chen Zhaohui; Huang Zhenjun; Yang Zhihua
通讯作者: Pan, SL
关键词: Pb6B3O10X (X=F, Cl, Br) ; Oxyborates ; Crystal structures ; Syntheses ; Optical properties
刊名: JOURNAL OF SOLID STATE CHEMISTRY
发表日期: 2013
DOI: 10.1016/j.jssc.2013.05.016
卷: 204, 期:8, 页:64-69
收录类别: SCI
资助者: 973 Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of CAS KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of CAS; The Funds for Creative Cross & Cooperation Teams of CAS; Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period 201130111; High Technology Research & Development Program of Xinjiang Uygur Autonomous Region of China 201116143; Science and Technology Project of Urumqi G121130002
摘要: A series of lead-containing halogen oxyborates, Pb6B3O10X (X=F, Cl, Br), have been grown by high-temperature solution method and their crystal structures were determined by single-crystal X-ray diffraction. They are isostructural and crystallize in the space group Pbcm of the orthorhombic crystal system. The crystal structures are dominated by one-dimensional (infinity)(Pb4O)(BO3)(3)"Zig-Zag"-chains, while the remaining Pb atoms and X (X=F, Cl, Br) atoms are filled to balance the charge. Compared with the previously reported compound Pb4O(BO3)(2) (the molecular formula Pb4O(BO3)(2) can be regarded as Pb6B3O10.5) with the space group Aba2, the structures of Pb6B3O10X (X=F, Cl, Br) are completely different from that of Pb4O(BO3)(2). IR spectroscopy, UV vis-NIR diffuse reflectance spectroscopy, thermal analysis, and theoretical calculations were also performed on the reported materials. Crown Copyright (C) 2013 Published by Elsevier Inc. All rights reserved.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2642
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Dong Lingyun,Pan Shilie,Wu Hongping,et al. Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)[J]. JOURNAL OF SOLID STATE CHEMISTRY,2013,204(8):64-69.
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