Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)
Dong Lingyun; Pan Shilie; Wu Hongping; Su Xin; Yu Hongwei; Wang Ying; Chen Zhaohui; Huang Zhenjun; Yang Zhihua; Pan, SL
2013
发表期刊JOURNAL OF SOLID STATE CHEMISTRY
ISSN0022-4596
卷号204期号:8页码:64-69
摘要A series of lead-containing halogen oxyborates, Pb6B3O10X (X=F, Cl, Br), have been grown by high-temperature solution method and their crystal structures were determined by single-crystal X-ray diffraction. They are isostructural and crystallize in the space group Pbcm of the orthorhombic crystal system. The crystal structures are dominated by one-dimensional (infinity)(Pb4O)(BO3)(3)"Zig-Zag"-chains, while the remaining Pb atoms and X (X=F, Cl, Br) atoms are filled to balance the charge. Compared with the previously reported compound Pb4O(BO3)(2) (the molecular formula Pb4O(BO3)(2) can be regarded as Pb6B3O10.5) with the space group Aba2, the structures of Pb6B3O10X (X=F, Cl, Br) are completely different from that of Pb4O(BO3)(2). IR spectroscopy, UV vis-NIR diffuse reflectance spectroscopy, thermal analysis, and theoretical calculations were also performed on the reported materials.
关键词Oxyborates Pb6b3o10x (X=f Crystal Structures Cl Syntheses Br) Optical Properties
学科领域Chemistry
DOI10.1016/j.jssc.2013.05.016
收录类别SCI
WOS记录号WOS:000322932600011
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被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2642
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Dong Lingyun,Pan Shilie,Wu Hongping,et al. Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)[J]. JOURNAL OF SOLID STATE CHEMISTRY,2013,204(8):64-69.
APA Dong Lingyun.,Pan Shilie.,Wu Hongping.,Su Xin.,Yu Hongwei.,...&Pan, SL.(2013).Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br).JOURNAL OF SOLID STATE CHEMISTRY,204(8),64-69.
MLA Dong Lingyun,et al."Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)".JOURNAL OF SOLID STATE CHEMISTRY 204.8(2013):64-69.
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