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学科主题: Chemistry
题名:
Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br
作者: Chen Zhaohui; Pan ShiLie(潘世烈); Dong Xiaoyu; Yang Zhihua; Zhang Min; Su Xin
通讯作者: Pan, SL
关键词: Na3B6O10Br ; Synthesis ; Crystal and electronic structures ; Borate
刊名: INORGANICA CHIMICA ACTA
发表日期: 2013
DOI: 10.1016/j.ica.2013.04.046
卷: 406, 期:9, 页:205-210
收录类别: SCI
英文摘要:

A new bromoborate Na3B6O10Br has been synthesized by the high temperature solution method. It crystallizes in orthorhombic space group Pnma (No. 53) with lattice constants a = 12.780(8) angstrom, b = 9.914(6) angstrom, c = 7.518(2) angstrom, Z = 4. The crystal structure contains an infinite three-dimensional matrix that is built from B6O13 units, Na(1)O4Br2, Na(2)O6Br, and Na(3)O-6 polyhedra. Interestingly, four B6O13 units are interconnected by oxygen atoms forming hexadecagon huge pores. IR spectrum, UV-Vis-NIR diffuse reflectance spectrum, and thermogravimetric analyses for the compound are also presented, as are band structures and density of states calculations.

WOS记录号: WOS:000324325200028
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2639
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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Exploration of a new compound in the M-B-O-X (M alkali metals; X halogen) system Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br.pdf(1782KB)期刊论文作者接受稿开放获取View 联系获取全文

作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Xinjiang Univ, Phys & Chem Testing Ctr, Urumqi 830046, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Chen Zhaohui,Pan Shilie,Dong Xiaoyu,et al. Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br[J]. INORGANICA CHIMICA ACTA,2013-01-01,406(9):205-210.
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文件名: Exploration of a new compound in the M-B-O-X (M alkali metals; X halogen) system Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br.pdf
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