Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br
Chen Zhaohui; Pan Shilie; Dong Xiaoyu; Yang Zhihua; Zhang Min; Su Xin; Pan, SL
2013
发表期刊INORGANICA CHIMICA ACTA
ISSN0020-1693
卷号406期号:9页码:205-210
摘要

A new bromoborate Na3B6O10Br has been synthesized by the high temperature solution method. It crystallizes in orthorhombic space group Pnma (No. 53) with lattice constants a = 12.780(8) angstrom, b = 9.914(6) angstrom, c = 7.518(2) angstrom, Z = 4. The crystal structure contains an infinite three-dimensional matrix that is built from B6O13 units, Na(1)O4Br2, Na(2)O6Br, and Na(3)O-6 polyhedra. Interestingly, four B6O13 units are interconnected by oxygen atoms forming hexadecagon huge pores. IR spectrum, UV-Vis-NIR diffuse reflectance spectrum, and thermogravimetric analyses for the compound are also presented, as are band structures and density of states calculations.

关键词Na3b6o10br Synthesis Crystal And Electronic Structures Borate
学科领域Chemistry
DOI10.1016/j.ica.2013.04.046
收录类别SCI
WOS记录号WOS:000324325200028
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2639
专题新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Xinjiang Univ, Phys & Chem Testing Ctr, Urumqi 830046, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Chen Zhaohui,Pan Shilie,Dong Xiaoyu,et al. Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br[J]. INORGANICA CHIMICA ACTA,2013,406(9):205-210.
APA Chen Zhaohui.,Pan Shilie.,Dong Xiaoyu.,Yang Zhihua.,Zhang Min.,...&Pan, SL.(2013).Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br.INORGANICA CHIMICA ACTA,406(9),205-210.
MLA Chen Zhaohui,et al."Exploration of a new compound in the M-B-O-X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br".INORGANICA CHIMICA ACTA 406.9(2013):205-210.
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