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学科主题: Chemistry
题名: Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9
作者: Zhou Lin; Pan Shilie; Su Xin; Yang Zhihua; Wu Hongping; Yu Hongwei; Zhang Fangfang; Cui Sifang; Zhou Zhongxiang
通讯作者: Pan, SL
关键词: KPbB5O9 ; Synthesis ; Crystal structure ; Theoretical calculations
刊名: JOURNAL OF MOLECULAR STRUCTURE
发表日期: 2013
DOI: 10.1016/j.molstruc.2013.06.071
卷: 1049, 期:10, 页:473-478
收录类别: SCI
资助者: 973 Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of CAS KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of CAS; Funds for Creative Cross & Cooperation Teams of CAS, Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period 201130111; High Technology Research & Development Program of Xinjiang Uygur Autonomous Region of China 201116143; Science and Technology Project of Urumqi G121130002
摘要: A new potassium lead pentaborate compound, KPbB5O9 has been synthesized by standard solid-state reaction for the first time. Its structure has been determined by single-crystal X-ray diffraction method. It crystallizes in the monoclinic space group P2(1)/c with lattice constants a = 6.717(3) angstrom, b = 8.389(3) angstrom, c = 13.686(5) angstrom, beta = 94.679(4)degrees and Z = 4. The structure consists of double ring B5O9 units, KO8 and PbO6 polyhedra. The PbO6 polyhedra linked together via corner-sharing O atom forming novel infinite (infinity)PbO6 chains along the b axis. Thermal analyses, IR spectroscopy and UV-vis-NIR diffuse reflectance spectrum, and band structure calculation were performed.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2631
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100039, Peoples R China;Huazhong Univ Sci & Technol, Sch Opt & Elect Informat, Wuhan 430074, Peoples R China

Recommended Citation:
Zhou Lin,Pan Shilie,Su Xin,et al. Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9[J]. JOURNAL OF MOLECULAR STRUCTURE,2013,1049(10):473-478.
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文件名: Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9.pdf
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