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乙酸中碘催化氧化苄醇为相应醛或酮(英文)
Alternative Titlelodine-catalyzed aerobic oxidation of alcohols to corresponding aldehydes or ketones in acetic acid
Shang Jie; Zhao Wenjun; Wang Xu; Wang Hua; Yang Danhong
2010
Source PublicationJournal of Molecular Catalysis(China)
ISSN1001-3555
Volume24Issue:5
Abstract本文报道了用I2/NaNO2/4-OH-TEMPO为催化剂,空气为氧化剂,在冰乙酸中催化氧化苄醇的方法.文中考察了催化剂各组分和温度对催化氧化反 应的影响,在催化过程中碘替代过渡金属作为4-OH-TEMPO的共催化剂,在选择条件下苄醇氧反应的产物产率达到90%,在反应过程中生成醛或酮
Other AbstractAn efficient aerobic oxidation of alcohols to corresponding aldehydes or ketones by the catalyzed system of I2/NaNO2/4-OH-TEMPO in the presence of acetic acid was investigated. The influence of each component and the amount of catalyst were studied. Iodine is used as co-catalyst instead of metal in the reaction. Aerobic oxidations of benzylic alcohols were almost completed under optimized conditions and the product with yield of 90% can be obtained
Keyword 苄醇 空气
Subject AreaChemistry (Provided By Thomson Reuters)
DOI10.16084/j.cnki.issn1001-3555.2010.05.003
Indexed ByCSCD
CSCD IDCSCD:4064521
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2617
Collection资源化学研究室
Affiliation中国科学院新疆理化技术研究所;中国科学院研究生院
Recommended Citation
GB/T 7714
Shang Jie,Zhao Wenjun,Wang Xu,等. 乙酸中碘催化氧化苄醇为相应醛或酮(英文)[J]. Journal of Molecular Catalysis(China),2010,24(5).
APA Shang Jie,Zhao Wenjun,Wang Xu,Wang Hua,&Yang Danhong.(2010).乙酸中碘催化氧化苄醇为相应醛或酮(英文).Journal of Molecular Catalysis(China),24(5).
MLA Shang Jie,et al."乙酸中碘催化氧化苄醇为相应醛或酮(英文)".Journal of Molecular Catalysis(China) 24.5(2010).
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