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学科主题: Chemistry (provided by Thomson Reuters)
题名: 乙酸中碘催化氧化苄醇为相应醛或酮(英文)
其他题名: lodine-catalyzed aerobic oxidation of alcohols to corresponding aldehydes or ketones in acetic acid
作者: Shang Jie; Zhao Wenjun; Wang Xu; Wang Hua; Yang Danhong
关键词: ; 苄醇 ; 空气
刊名: Journal of Molecular Catalysis(China)
发表日期: 2010
DOI: 10.16084/j.cnki.issn1001-3555.2010.05.003
卷: 24, 期:5
收录类别: CSCD
资助者: Project (200821158) supported by the Xinjiang Provincial Natural Science Foundation of China
摘要: 本文报道了用I2/NaNO2/4-OH-TEMPO为催化剂,空气为氧化剂,在冰乙酸中催化氧化苄醇的方法.文中考察了催化剂各组分和温度对催化氧化反 应的影响,在催化过程中碘替代过渡金属作为4-OH-TEMPO的共催化剂,在选择条件下苄醇氧反应的产物产率达到90%,在反应过程中生成醛或酮
英文摘要: An efficient aerobic oxidation of alcohols to corresponding aldehydes or ketones by the catalyzed system of I2/NaNO2/4-OH-TEMPO in the presence of acetic acid was investigated. The influence of each component and the amount of catalyst were studied. Iodine is used as co-catalyst instead of metal in the reaction. Aerobic oxidations of benzylic alcohols were almost completed under optimized conditions and the product with yield of 90% can be obtained
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2617
Appears in Collections:资源化学研究室_期刊论文

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作者单位: 中国科学院新疆理化技术研究所;中国科学院研究生院

Recommended Citation:
Shang Jie,Zhao Wenjun,Wang Xu,等. 乙酸中碘催化氧化苄醇为相应醛或酮(英文)[J]. Journal of Molecular Catalysis(China),2010,24(5).
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