Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)(2)F2Cl and Noncentrosymmetric NaBa4(AlB4O9)(2)Br-3
Yu, HW (Yu, Hongwei); Pan, SL (Pan, Shilie); Wu, HP (Wu, Hongping); Yang, ZH (Yang, Zhihua); Dong, LY (Dong, Lingyun); Su, X (Su, Xin); Zhang, BB (Zhang, Bingbing); Li, HY (Li, Hongyi)
2013
Source PublicationCRYSTAL GROWTH & DESIGN
ISSN1528-7483
Volume13Issue:8Pages:3514-3521
Abstract

Two similarly stoichiometric borate halides, NaBa4(AlB4O9)(2)Br-3 and NaBa4(B5O9)(2)F2Cl, have been successfully designed and synthesized, and their structures were determined by single-crystal X-ray diffraction. Their crystal structures feature the [AlB4O9],, and [B5O9], networks, respectively. NaBa4(AlB4O9)(2)Br-3 is noncentrosymmetric and crystallizes in polar space group P4(2)nm, while NaBa4(B5O9)(2)F2Cl is centrosymmetric and crystallizes in monoclinic space group P2(1)/n. Powder second-harmonic generation (SHG) measurements reveal that NaBa4(AlB4O9)(2)Br-3 has an optical non-linearity comparable to that of KH2PO4 (ICDP) and is type I phase-matchable. In addition, infrared and UV-Vis-NIR diffuse reflectance spectroscopy, as well as electronic band structure calculations, were performed on the reported materials.

DOI10.1021/cg4004774
Indexed BySCI
WOS IDWOS:000323020000031
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2555
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
2.Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yu, HW ,Pan, SL ,Wu, HP ,et al. Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)(2)F2Cl and Noncentrosymmetric NaBa4(AlB4O9)(2)Br-3[J]. CRYSTAL GROWTH & DESIGN,2013,13(8):3514-3521.
APA Yu, HW .,Pan, SL .,Wu, HP .,Yang, ZH .,Dong, LY .,...&Li, HY .(2013).Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)(2)F2Cl and Noncentrosymmetric NaBa4(AlB4O9)(2)Br-3.CRYSTAL GROWTH & DESIGN,13(8),3514-3521.
MLA Yu, HW ,et al."Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)(2)F2Cl and Noncentrosymmetric NaBa4(AlB4O9)(2)Br-3".CRYSTAL GROWTH & DESIGN 13.8(2013):3514-3521.
Files in This Item:
File Name/Size DocType Version Access License
Effect of Rigid Unit(2268KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yu, HW (Yu, Hongwei)]'s Articles
[Pan, SL (Pan, Shilie)]'s Articles
[Wu, HP (Wu, Hongping)]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yu, HW (Yu, Hongwei)]'s Articles
[Pan, SL (Pan, Shilie)]'s Articles
[Wu, HP (Wu, Hongping)]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yu, HW (Yu, Hongwei)]'s Articles
[Pan, SL (Pan, Shilie)]'s Articles
[Wu, HP (Wu, Hongping)]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Effect of Rigid Units on the Symmetry of the Framework Design and Synthesis of Centrosymmetric NaBa4(B5O9)(2)F2Cl and Noncentrosymmetric NaBa4(AlB4O9)(2)Br-3.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.