New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles
Yu, HW (Yu, Hongwei); Wu, HP (Wu, Hongping); Pan, SL (Pan, Shilie); Wang, Y (Wang, Ying); Yang, ZH (Yang, Zhihua); Su, X (Su, Xin)
2013
Source PublicationInorganic Chemistry
ISSN0020-1669
Volume52Issue:9Pages:5359-5365   
Abstract

Introduction of the coplanar BO3 triangles in the alkali metal and alkaline-earth metal mixed fluoborate generates a new UV nonlinear optical material [Li3Ca9(BO3)(7)]center dot 2[LiF] (LCBF), which possesses a moderate SHG response as large as that of the KDP and a wide transparent region with a UV cutoff edge at 230 nm. The first-principle theoretical calculation suggests that LCBF has a relatively large birefringence (0.07; 532 nm). These properties make it a potential UV nonlinear optical material. And interestingly, LCBF is a salt-inclusion borate with the Li-F chains residing in the one-dimensional open framework, which caters to the development of the salt-inclusion compound in borate.

DOI10.1021/ic4002779
Indexed BySCI
WOS IDWOS:000318669400073
Citation statistics
Cited Times:34[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2552
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan, SL (Pan, Shilie)
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yu, HW ,Wu, HP ,Pan, SL ,et al. New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles[J]. Inorganic Chemistry,2013,52(9):5359-5365   .
APA Yu, HW ,Wu, HP ,Pan, SL ,Wang, Y ,Yang, ZH ,&Su, X .(2013).New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles.Inorganic Chemistry,52(9),5359-5365   .
MLA Yu, HW ,et al."New Salt-Inclusion Borate, Li3Ca9(BO3)(7)center dot 2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles".Inorganic Chemistry 52.9(2013):5359-5365   .
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