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题名: BaClBF4: a new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage threshold
作者: Min Zhang,Shilie Pan,Zhihua Yang,Ying Wang,Xin Su, Yun Yang,Zhenjun Huang, Shujuan Han and Kenneth R. Poeppelmeier
通讯作者: Pan, SL
刊名: Journal of Materials Chemistry C
发表日期: 2013
DOI: 10.1039/c3tc30581c
卷: 1, 期:31, 页:4740-4745
收录类别: SCI
摘要: A new noncentrosymmetric alkaline earth metal halide borate, BaClBF4, has been synthesized with crystal size up to 6 mm × 6 mm × 3 mm via the hydrothermal method at 200 °C. The crystal structure can be described as an alternate stacking of cationic [Ba2Cl2]2+ layers with anionic [BF4]− layers along the b direction, and the [Ba2Cl2]2+ layer is a pseudo-Aurivillius type layer similar to the [Bi2O2]2+ layer. The transmittance range of BaClBF4 is from 0.18 to 8.5 μm, and the laser damage threshold of the crystal is about 6.8 GW cm−2. EDS, TG-DSC and second harmonic generation investigations are reported. The electronic structure is discussed to explain the structure–property relationships.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2549
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China; Univ Chinese Acad Sci, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

Recommended Citation:
Min Zhang,Shilie Pan,Zhihua Yang,Ying Wang,Xin Su, Yun Yang,Zhenjun Huang, Shujuan Han and Kenneth R. Poeppelmeier. BaClBF4: a new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage threshold[J]. Journal of Materials Chemistry C,2013,1(31):4740-4745.
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文件名: BaClBF4 a new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage threshold.pdf
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