BaClBF4: a new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage threshold
Min Zhang,Shilie Pan,Zhihua Yang,Ying Wang,Xin Su, Yun Yang,Zhenjun Huang, Shujuan Han and Kenneth R. Poeppelmeier; Pan, SL
2013
发表期刊Journal of Materials Chemistry C
卷号1期号:31页码:4740-4745
摘要

A new noncentrosymmetric alkaline earth metal halide borate, BaClBF4, has been synthesized with crystal size up to 6 mm x 6 mm x 3 mm via the hydrothermal method at 200 degrees C. The crystal structure can be described as an alternate stacking of cationic [Ba2Cl2](2+) layers with anionic [BF4](-) layers along the b direction, and the [Ba2Cl2](2+) layer is a pseudo-Aurivillius type layer similar to the [Bi2O2](2+) layer. The transmittance range of BaClBF4 is from 0.18 to 8.5 mu m, and the laser damage threshold of the crystal is about 6.8 GW cm(-2). EDS, TG-DSC and second harmonic generation investigations are reported. The electronic structure is discussed to explain the structure-property relationships.

DOI10.1039/c3tc30581c
收录类别SCI
WOS记录号WOS:000322028700017
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被引频次:20[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2549
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China; Univ Chinese Acad Sci, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
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Min Zhang,Shilie Pan,Zhihua Yang,Ying Wang,Xin Su, Yun Yang,Zhenjun Huang, Shujuan Han and Kenneth R. Poeppelmeier,Pan, SL. BaClBF4: a new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage threshold[J]. Journal of Materials Chemistry C,2013,1(31):4740-4745.
APA Min Zhang,Shilie Pan,Zhihua Yang,Ying Wang,Xin Su, Yun Yang,Zhenjun Huang, Shujuan Han and Kenneth R. Poeppelmeier,&Pan, SL.(2013).BaClBF4: a new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage threshold.Journal of Materials Chemistry C,1(31),4740-4745.
MLA Min Zhang,Shilie Pan,Zhihua Yang,Ying Wang,Xin Su, Yun Yang,Zhenjun Huang, Shujuan Han and Kenneth R. Poeppelmeier,et al."BaClBF4: a new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage threshold".Journal of Materials Chemistry C 1.31(2013):4740-4745.
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