Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response
Wu, HP (Wu, Hongping); Yu, HW (Yu, Hongwei); Yang, ZH (Yang, Zhihua); Hou, XL (Hou, Xueling); Su, X (Su, Xin); Pan, SL (Pan, Shilie); Poeppelmeier, KR (Poeppelmeier, Kenneth R.); Rondinelli, JM (Rondinelli, James M.
2013
Source PublicationJournal of the American Chemical Society 
ISSN0002-7863
Volume135Issue:11Pages:4215-4218   
Abstract

The generation of intense coherent deep-UV light from nonlinear optical materials is crucial to applications ranging from semiconductor photolithography and laser micromachining to photochemical synthesis. However, few materials with large second harmonic generation (SHG) and a short UV-cutoff edge are effective down to 200 nm. A notable exception is KBe2BO3F2, which is obtained from a solid-state reaction of highly toxic beryllium oxide powders. We designed and synthesized a benign polar material, Ba4B11O20F, that satisfies these requirements and exhibits the largest SHG response in known borates containing neither lone-pair-active anions nor second-order Jahn-Teller-active transition metals. We developed a microscopic model to explain the enhancement, which is unexpected on the basis of conventional anionic group theory arguments. Crystal engineering of atomic displacements along the polar axis, which are difficult to attribute to or identify within unique anionic moieties, and greater cation polarizabilities are critical to the design of next-generation SHG materials.

DOI10.1021/ja400500m
Indexed BySCI
WOS IDWOS:000316774100014
Citation statistics
Cited Times:290[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2545
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
资源化学研究室
材料物理与化学研究室
Corresponding AuthorPan, SL (Pan, Shilie)
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA;Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
Recommended Citation
GB/T 7714
Wu, HP ,Yu, HW ,Yang, ZH ,et al. Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response[J]. Journal of the American Chemical Society ,2013,135(11):4215-4218   .
APA Wu, HP .,Yu, HW .,Yang, ZH .,Hou, XL .,Su, X .,...&Rondinelli, JM .(2013).Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response.Journal of the American Chemical Society ,135(11),4215-4218   .
MLA Wu, HP ,et al."Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response".Journal of the American Chemical Society  135.11(2013):4215-4218   .
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