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取代基对N-羟基邻苯二甲酰亚胺催化环己烷氧化活性的影响
杨丹红; 文彬
2012
Source Publication应用化工
ISSN1671-3206
Volume41Issue:11Pages:1898-1900
Abstract

合成了一系列吸电子基团和供电子基团取代的N-羟基邻苯二甲酰亚胺(X-NHPI),研究了芳环上的取代基对NHPI在环己烷选择氧化反应中催化活性的影响。结果表明,吸电子基团可以增强NHPI的催化活性,吸电子能力越强,催化活性越高;供电子基团则降低了NHPI的催化活性。

Other Abstract

A series of aryl-substituted N-hydroxyphthalimides ( X-NHPI) containing both electron-withdrawing groups and electron-donating groups have been synthesized. The effect of substitution in the aromatic ring of N-hydroxyphthalimide on catalytic activity in cyclohexane oxidation has been tested. The results showed that the electron-withdrawing groups enhance the catalytic activity of the NHPI, the electronwithdrawing ability was stronger. On the other hand, the electron-donating groups decrease the catalytic activity of the NHPI.

Keyword取代 Nhpi 环己烷 氧化
DOI10.16581/j.cnki.issn1671-3206.2012.11.022
Indexed ByCSCD
CSCD IDCSCD:4707570
Citation statistics
Cited Times:1[CSCD]   [CSCD Record]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2428
Collection资源化学研究室
Affiliation中国科学院新疆理化技术研究所
Recommended Citation
GB/T 7714
杨丹红,文彬. 取代基对N-羟基邻苯二甲酰亚胺催化环己烷氧化活性的影响[J]. 应用化工,2012,41(11):1898-1900.
APA 杨丹红,&文彬.(2012).取代基对N-羟基邻苯二甲酰亚胺催化环己烷氧化活性的影响.应用化工,41(11),1898-1900.
MLA 杨丹红,et al."取代基对N-羟基邻苯二甲酰亚胺催化环己烷氧化活性的影响".应用化工 41.11(2012):1898-1900.
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