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学科主题: Chemistry
题名: Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units
作者: Yunjing Shi,Shilie Pan,,Xiaoyu Dong,Ying Wang,Min Zhang,Fangfang Zhang,and Zhongxiang Zhou
通讯作者: Pan, SL
刊名: INORGANIC CHEMISTRY
发表日期: 2012
DOI: 10.1021/ic301351k
卷: 51, 期:20, 页:10870-10875
收录类别: SCI
摘要: A new noncentrosymmetric borophosphate, Na3Cd3B(PO4)(4), has been successfully synthesized by conventional solid state reaction for the first time. It crystallizes in the orthorhombic space group Pmc2(1) with unit cell parameters of a = 13.6854(3) angstrom, b = 5.3346(11) angstrom, c = 18.2169(4) angstrom, and Z = 4. Na3Cd3B(PO4)(4) features zero-dimensional [B(PO4)(4)](9-) anion units with Cd2+ and Na+/Cd2+ cations located around them, in which the BO4 tetrahedron is surrounded by four PO4 tetrahedra by sharing the vertexes of O atoms. Second harmonic generation (SHG) measurements show that Na3Cd3B(PO4)(4) exhibits a SHG response 1.1 times larger than that of KH2PO4 (KDP) and is phase matchable
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2283
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100039, Peoples R China

Recommended Citation:
Yunjing Shi,Shilie Pan,,Xiaoyu Dong,Ying Wang,Min Zhang,Fangfang Zhang,and Zhongxiang Zhou. Na3Cd3B(PO4)(4): A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units[J]. INORGANIC CHEMISTRY,2012,51(20):10870-10875.
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文件名: Na3Cd3B(PO4)(4) A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units.pdf
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