在微波辐射下过氧乙酸氧化合成壬二酸
Alternative Titlesynthesis of azelaic acid with peracetic acid under microwave irradiation
高军军; 张亚刚; 吾满江.艾力; 胡书明; 马莉
2005
Source Publication化学世界
ISSN0367-6358
Volume46Issue:11Pages:678-681
Abstract

以油酸为原料,50%(质量分数)的过氧化氢为氧化剂,在异丙醇作为助催化剂的条件下,采用钨酸作为催化剂合成中间产物9,10-二羟基硬脂酸,当除去溶剂后,加入自制的过氧乙酸,在微波下反应60 min后,采用热水萃取,收率可以达到70.5%,纯度可以达到97.76%。当反应时间达到120 min时,收率可以达到74.6%。

Other Abstract

Using 50% aqueous hydrogen peroxide as oxidant, 2-propanol as cocatalyst, 9,10-dihydroxystearic acid was synthesized with oleic acid as raw material and tungstic acid as catalyst. The solvent was removed by vacuum distillation, and then peracetic acid was added. After reacting for 60 min under microwave irradiation, the product was extracted with hot water. The yield of the acid was 70.5% and the purity of the acid was up to 97.76%. When reacting for 120 min under microwave irradiation, the yield of acid was increased to 74.6 %.

Keyword微波辐射 壬二酸 双氧水
Subject AreaAcoustics (Provided By Thomson Reuters)
Indexed ByCSCD
CSCD IDCSCD:2217083
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2157
Collection新疆维吾尔自治区精细化工工程技术研究中心
资源化学研究室
Affiliation中国科学院新疆理化技术研究所; 中国科学院研究生院
Recommended Citation
GB/T 7714
高军军,张亚刚,吾满江.艾力,等. 在微波辐射下过氧乙酸氧化合成壬二酸[J]. 化学世界,2005,46(11):678-681.
APA 高军军,张亚刚,吾满江.艾力,胡书明,&马莉.(2005).在微波辐射下过氧乙酸氧化合成壬二酸.化学世界,46(11),678-681.
MLA 高军军,et al."在微波辐射下过氧乙酸氧化合成壬二酸".化学世界 46.11(2005):678-681.
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