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题名: Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14
作者: Pan Shilie; Smit Jared P.; Marvel Michael R.; Stampler Evan S.; Haag Jacob M.; Baek Jaewook; Halasyamani P. Shiv; Poeppelmeier Kenneth R.
通讯作者: Pan, SL
关键词: crystal growth ; crystal structure ; oxide ; nonlinear optical properties
刊名: Journal of Solid State Chemistry
发表日期: 2008
DOI: 10.1016/j.jssc.2008.05.008
卷: 181, 期:8, 页:2087-2091
收录类别: SCI
资助者: National Science Foundation;Department of Energy, BES-Chemical Sciences, Geosciences, and Biosciences Division;Materials Research Center of Northwestern UniversityWest Light Foundation of the Chinese Academy of SciencesWelch Foundation;NSF
摘要: Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a = 10.1381(11)angstrom, b = 9.3917(11)angstrom, c = 3.4566(4)angstrom, alpha = 105.570(2)(-), beta = 92.275(2)(-), gamma = 107.783(2), Z = 1 and R-1 = 0.0401 and w/R-2 = 0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90 degrees C. The Second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2037
Appears in Collections:材料物理与化学研究室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Xinjiang, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA;Univ Houston, Dept Chem, Houston, TX 77204 USA

Recommended Citation:
Pan Shilie,Smit Jared P.,Marvel Michael R.,et al. Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14[J]. Journal of Solid State Chemistry,2008,181(8):2087-2091.
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