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Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14
Pan Shilie; Smit Jared P.; Marvel Michael R.; Stampler Evan S.; Haag Jacob M.; Baek Jaewook; Halasyamani P. Shiv; Poeppelmeier Kenneth R.
2008
Source PublicationJournal of Solid State Chemistry
ISSN0022-4596
Volume181Issue:8Pages:2087-2091
Abstract

Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a = 10.1381(11)angstrom, b = 9.3917(11)angstrom, c = 3.4566(4)angstrom, alpha = 105.570(2)(-), beta = 92.275(2)(-), gamma = 107.783(2), Z = 1 and R-1 = 0.0401 and w/R-2 = 0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90 degrees C. The Second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.

KeywordCrystal Growth Crystal Structure Oxide Nonlinear Optical Properties
DOI10.1016/j.jssc.2008.05.008
Indexed BySCI
WOS IDWOS:000259098000052
Citation statistics
Cited Times:29[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2037
Collection材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Xinjiang, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA;Univ Houston, Dept Chem, Houston, TX 77204 USA
Recommended Citation
GB/T 7714
Pan Shilie,Smit Jared P.,Marvel Michael R.,et al. Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14[J]. Journal of Solid State Chemistry,2008,181(8):2087-2091.
APA Pan Shilie.,Smit Jared P..,Marvel Michael R..,Stampler Evan S..,Haag Jacob M..,...&Poeppelmeier Kenneth R..(2008).Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14.Journal of Solid State Chemistry,181(8),2087-2091.
MLA Pan Shilie,et al."Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14".Journal of Solid State Chemistry 181.8(2008):2087-2091.
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