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Alternative TitleEffect of Solvent on Cyelohexane Oxidation
杨丹红; 赵文军; 高林
Source Publication石油化工


Other Abstract

Effect of solvents, namely acetic acid, acetonitrile and ionic liquids (IL), on oxidation of cyclohexane was investigated and iron porphyrin was used as catalyst. All solvents mentioned above improves conversions of cyclohexane, among which IL is the best, followed by acetonitrile and then acetic acid. Conversion of cyclohexane increases along with acidity of IL. Under conditions of 145°C, O2 pressure 0.8 MPa, 3 h, 5 mg catalyst in 25 mL of N-butylsulfonic acid pyridinium hydrogen sulfate, conversion of cyclohexane is 20.8%, and selectivity to KA oil (cyclohexanol and cyclohexanone) is 82.6%. The products can be separated with EL by decantation. The IL can be reused for three times after removal of water under vacuum.

Keyword环己烷 氧化反应 溶剂效应 离子液体 乙酸 乙腈
Indexed ByCSCD
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Cited Times:1[CSCD]   [CSCD Record]
Document Type期刊论文
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GB/T 7714
杨丹红,赵文军,高林. 环己烷氧化反应中的溶剂效应[J]. 石油化工,2008,37(2):136-139.
APA 杨丹红,赵文军,&高林.(2008).环己烷氧化反应中的溶剂效应.石油化工,37(2),136-139.
MLA 杨丹红,et al."环己烷氧化反应中的溶剂效应".石油化工 37.2(2008):136-139.
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