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Synthesis and characterization of LiCo1/3Ni1/3Mn1/3O2 prepared by Pechini process
Li Zhigang; Wang Tiandiao; Kang Xueya; Kang, XY
2006
Source PublicationRare Metals
ISSN10010521
Volume25Issue:6 SUPPL. 1Pages:41101
AbstractLayered cathode material LiCo1/3Ni1/3 Mn1/3O2 was synthesized by Pechini process, and investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) and galvanostatic charge/discharge cycling. The sample is well-crystallized and has a phase-pure a-NaFeO2 structure. The particle sizes are uniform, and distributed in the range of 20-200 nm. The initial discharge capacity of the Li/LiCo1/3Ni1/3 Mn1/3O2 cell was about 149 mAh·g-1 when it was cycled at a voltage range of 4.5-2.3 V with a specific current of 0.25 mA. The result is better in comparison with solid-state solution method. The synthetic procedure was discussed. Three major reactions: chelation, esterification, and polymerization successively occurred.
KeywordLayered Cathode Material Lico1/3ni1/3mn1/3o2 Pechini Method Structure Morphology Electrochemical Properties
DOI10.1016/S1001-0521(07)60036-9
Indexed BySCI
WOS IDWOS:000242948100002
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1988
Collection材料物理与化学研究室
Corresponding AuthorKang, XY
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li Zhigang,Wang Tiandiao,Kang Xueya,et al. Synthesis and characterization of LiCo1/3Ni1/3Mn1/3O2 prepared by Pechini process[J]. Rare Metals,2006,25(6 SUPPL. 1):41101.
APA Li Zhigang,Wang Tiandiao,Kang Xueya,&Kang, XY.(2006).Synthesis and characterization of LiCo1/3Ni1/3Mn1/3O2 prepared by Pechini process.Rare Metals,25(6 SUPPL. 1),41101.
MLA Li Zhigang,et al."Synthesis and characterization of LiCo1/3Ni1/3Mn1/3O2 prepared by Pechini process".Rare Metals 25.6 SUPPL. 1(2006):41101.
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