两种新型Brφnsted酸性离子液体的合成与表征
李涛; 李心琮; 阎海龙; 黄成坤; 吾满江·艾力
2007
Source Publication化学试剂
ISSN0258-3283
Volume29Issue:6Pages:358-360
Abstract

以β-氯乙基苯醚、苄氯、N-甲基咪唑、浓硫酸等为原料,通过多步反应合成了在N-甲基咪唑阳离子上分别含烷氧基苯磺酸和烷基苯磺酸侧链结构的两种水溶性、室温下呈液相的新型Brφnsted酸性离子液体,总产率分别为79.8%和83.6%。选配的阴离子为[HSO4]-,进一步增加了离子液体的酸性。产物结构通过红外光谱、核磁共振氢谱得以确认。

Other Abstract

Two novel water and air stable Bronsted-acidic ionic liquids were synthesized.One had an alkoxy benzene sulfonic acid group in the N-methylimidazolium cation,and the other possessed an alkyl benzene sulfonic acid group in the N-methylimidazolium cation.The counteranions were [HSO_4]-for both compounds.The total yield was 79.8% and 83.6%,respectively. All the compounds were new,and their structure was confirmed by IR spectrometry and ~1HNMR.

Keyword离子液体 苯磺酸 催化剂 Brphinsted酸
Indexed ByCSCD
CSCD IDCSCD:2826512
Citation statistics
Cited Times:1[CSCD]   [CSCD Record]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1984
Collection新疆维吾尔自治区精细化工工程技术研究中心
Affiliation中国科学院新疆理化技术研究所;中国科学院研究生院
Recommended Citation
GB/T 7714
李涛,李心琮,阎海龙,等. 两种新型Brφnsted酸性离子液体的合成与表征[J]. 化学试剂,2007,29(6):358-360.
APA 李涛,李心琮,阎海龙,黄成坤,&吾满江·艾力.(2007).两种新型Brφnsted酸性离子液体的合成与表征.化学试剂,29(6),358-360.
MLA 李涛,et al."两种新型Brφnsted酸性离子液体的合成与表征".化学试剂 29.6(2007):358-360.
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