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新型Salen-卟啉金属配合物催化剂的研究
苏建玲; 赵文军; 张富昌; 高利柱; 高林
2007
Source Publication应用化工
ISSN1671-3206
Volume36Issue:4Pages:390-393
Abstract

以5-对氨基苯基-10,15,20-三苯基卟啉和水杨醛为原料,合成水杨醛缩氨基四苯基卟啉,分别加入Ni(NO3).26H2O和Mn(OAc)2.4H2O,经络合反应,合成了两个同时具有卟啉结构和Salen结构的配合物3a和3b,产率分别为75%和80%,各化合物均通过UV-Vis,IR,1HNMR,元素分析进行表征。将配合物3a和3b应用于环己烷的催化氧化,环己烷的转化率分别达到了8.25%和12.45%。

Other Abstract

The radiation dose characteristics of optically stimulated luminescence material CaS:Ce, Sm is researched. The CaS:Ce, Sm/PMMA dosimeter sheet was irradiated by a 60Co γ-radiation source, and the fluorescence signal from dosimeter sheet was measured with the test system built by ourselves. The result indicates that CaS:Ce, Sm is short afterglow material and the influence of environment temperature on the material is very obvious. The intensity of fluorescence signal peak value and the adsorbed dose have a good linear relation in the scope of 0.1-100 Gy.

Keyword卟啉 席夫碱 配合物 二聚体
DOI10.16581/j.cnki.issn1671-3206.2007.04.024
Indexed ByCSCD
CSCD IDCSCD:2888785
Citation statistics
Cited Times:1[CSCD]   [CSCD Record]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1978
Collection资源化学研究室
Affiliation中国科学院新疆理化技术研究所;中国科学院研究生院
Recommended Citation
GB/T 7714
苏建玲,赵文军,张富昌,等. 新型Salen-卟啉金属配合物催化剂的研究[J]. 应用化工,2007,36(4):390-393.
APA 苏建玲,赵文军,张富昌,高利柱,&高林.(2007).新型Salen-卟啉金属配合物催化剂的研究.应用化工,36(4),390-393.
MLA 苏建玲,et al."新型Salen-卟啉金属配合物催化剂的研究".应用化工 36.4(2007):390-393.
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