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Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O
Fan Xiaoyun; Pan Shilie; Hou Xueling; Liu Gang; Wang Jide
2009
发表期刊INORGANIC CHEMISTRY
ISSN0020-1669
卷号48期号:11页码:4806-4810
摘要

The synthesis, crystal structure, and characterization of the noncentrosymmetric semiorganic material (NH4)center dot SrL-(+)-C4H2O6 center dot B(OH)(2)center dot 4H(2)O were reported. Crystals were synthesized through slow evaporation at room temperature, utilizing SrCl2 center dot 6H(2)O, C4H4O6, H3BO3, and NH3, H2O as reagents, and its structure was determined by single-crystal X-ray diffraction. It crystallizes in the triclinic space group P1 (No. 1) with a=6.4633(10) angstrom, b=7.0452(13) angstrom, c = 7.0745(12) angstrom, alpha = 85.351(5), beta = 77.678(5), gamma = 73.276(4), and Z=1. It exhibits a two-dimensional layered structure along the c axis, consisting of SrO9 polyhedra, BO4 tetrahedra, tartrate molecules, NH4 cations, and H2O molecules. IR spectroscopy, UV-vis diffuse-reflectance spectroscopy, thermal analysis, and second-harmonic generation (SHG) were also performed on the reported material. Nonlinear optical measurements, using 1064 nm radiation, indicate that the material has SHG properties, with an efficiency of approximately 1.5 times that of KH2PO4.

学科领域Chemistry
DOI10.1021/ic802448z
收录类别SCI
WOS记录号WOS:000266428100041
引用统计
被引频次:38[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1886
专题材料物理与化学研究室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
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Fan Xiaoyun,Pan Shilie,Hou Xueling,et al. Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O[J]. INORGANIC CHEMISTRY,2009,48(11):4806-4810.
APA Fan Xiaoyun,Pan Shilie,Hou Xueling,Liu Gang,&Wang Jide.(2009).Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O.INORGANIC CHEMISTRY,48(11),4806-4810.
MLA Fan Xiaoyun,et al."Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O".INORGANIC CHEMISTRY 48.11(2009):4806-4810.
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