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Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O
Fan Xiaoyun; Pan Shilie; Hou Xueling; Liu Gang; Wang Jide
2009
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume48Issue:11Pages:4806-4810
Abstract

The synthesis, crystal structure, and characterization of the noncentrosymmetric semiorganic material (NH4)center dot SrL-(+)-C4H2O6 center dot B(OH)(2)center dot 4H(2)O were reported. Crystals were synthesized through slow evaporation at room temperature, utilizing SrCl2 center dot 6H(2)O, C4H4O6, H3BO3, and NH3, H2O as reagents, and its structure was determined by single-crystal X-ray diffraction. It crystallizes in the triclinic space group P1 (No. 1) with a=6.4633(10) angstrom, b=7.0452(13) angstrom, c = 7.0745(12) angstrom, alpha = 85.351(5), beta = 77.678(5), gamma = 73.276(4), and Z=1. It exhibits a two-dimensional layered structure along the c axis, consisting of SrO9 polyhedra, BO4 tetrahedra, tartrate molecules, NH4 cations, and H2O molecules. IR spectroscopy, UV-vis diffuse-reflectance spectroscopy, thermal analysis, and second-harmonic generation (SHG) were also performed on the reported material. Nonlinear optical measurements, using 1064 nm radiation, indicate that the material has SHG properties, with an efficiency of approximately 1.5 times that of KH2PO4.

Subject AreaChemistry
DOI10.1021/ic802448z
Indexed BySCI
WOS IDWOS:000266428100041
Citation statistics
Cited Times:39[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1886
Collection材料物理与化学研究室
资源化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
Recommended Citation
GB/T 7714
Fan Xiaoyun,Pan Shilie,Hou Xueling,et al. Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O[J]. INORGANIC CHEMISTRY,2009,48(11):4806-4810.
APA Fan Xiaoyun,Pan Shilie,Hou Xueling,Liu Gang,&Wang Jide.(2009).Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O.INORGANIC CHEMISTRY,48(11),4806-4810.
MLA Fan Xiaoyun,et al."Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O".INORGANIC CHEMISTRY 48.11(2009):4806-4810.
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