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学科主题: Chemistry
题名: Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O
作者: Fan Xiaoyun; Pan Shilie; Hou Xueling; Liu Gang; Wang Jide
通讯作者: Pan, SL
刊名: INORGANIC CHEMISTRY
发表日期: 2009
DOI: 10.1021/ic802448z
卷: 48, 期:11, 页:4806-4810
收录类别: SCI
资助者: National Natural Science Foundation of China;One hundred Talents Project Foundation Program;Western Light Joint Scholar Foundation Program of Chinese Academy of Sciences;Natural Science Foundation of Xinjiang Uygur Autonomous Region of China;High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China
摘要: The synthesis, crystal structure, and characterization of the noncentrosymmetric semiorganic material (NH4)center dot SrL-(+)-C4H2O6 center dot B(OH)(2)center dot 4H(2)O were reported. Crystals were synthesized through slow evaporation at room temperature, utilizing SrCl2 center dot 6H(2)O, C4H4O6, H3BO3, and NH3, H2O as reagents, and its structure was determined by single-crystal X-ray diffraction. It crystallizes in the triclinic space group P1 (No. 1) with a=6.4633(10) angstrom, b=7.0452(13) angstrom, c = 7.0745(12) angstrom, alpha = 85.351(5), beta = 77.678(5), gamma = 73.276(4), and Z=1. It exhibits a two-dimensional layered structure along the c axis, consisting of SrO9 polyhedra, BO4 tetrahedra, tartrate molecules, NH4 cations, and H2O molecules. IR spectroscopy, UV-vis diffuse-reflectance spectroscopy, thermal analysis, and second-harmonic generation (SHG) were also performed on the reported material. Nonlinear optical measurements, using 1064 nm radiation, indicate that the material has SHG properties, with an efficiency of approximately 1.5 times that of KH2PO4.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1886
Appears in Collections:材料物理与化学研究室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China

Recommended Citation:
Fan Xiaoyun,Pan Shilie,Hou Xueling,et al. Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O[J]. INORGANIC CHEMISTRY,2009,48(11):4806-4810.
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文件名: semiorganic nonlinear optical material preparation and properties of (nh4)center dot srl-(+)-c4h2o6 center dot b(oh)(2)center dot 4h(2)o.pdf
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