Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6
Li Feng; Hou Xueling; Pan Shilie; Wang Xian
2009
Source PublicationCHEMISTRY OF MATERIALS
ISSN0897-4756
Volume21Issue:13Pages:2846-2850
Abstract

A single crystal of Bi2ZnOB2O6 has been grown with sizes up to 18 x 13 x 6 mm(3) by the top-seeded growth method for the First time with high quality. It crystallizes in the orthorhombic system, space group Pba2 with unit-cell parameters a = 10.8200(7) angstrom, b = 11.00 14(7) angstrom, c = 4.8896(3) angstrom, Z = 4, V = 582.03(6) angstrom(3). Bi2ZnOB2O6 has a three-dimensional network consisting of ZnB2O76- layers alternating with six-coordinated Bi3+ cations along the c axis. Transmission spectrum of Bi2ZnOB2O6 crystal was reported. The refractive indices of the crystal were measured by the minimum deviation technique and fitted to the Sellmeier equations. The powder second-harmonic generation (SHG) properties measured by the Kurtz-Perry method indicate that Bi2ZnOB2O6 is phasematchable.

Subject AreaChemistry ; Materials Science
DOI10.1021/cm900560x
Indexed BySCI
WOS IDWOS:000268138200045
Citation statistics
Cited Times:86[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1883
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
资源化学研究室
Corresponding AuthorPan Shilie
Affiliation1.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Xi An Jiao Tong Univ, Elect Mat Res Lab, Key Lab, Minist Educ, Xian 710049, Peoples R China
Recommended Citation
GB/T 7714
Li Feng,Hou Xueling,Pan Shilie,et al. Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6[J]. CHEMISTRY OF MATERIALS,2009,21(13):2846-2850.
APA Li Feng,Hou Xueling,Pan Shilie,&Wang Xian.(2009).Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6.CHEMISTRY OF MATERIALS,21(13),2846-2850.
MLA Li Feng,et al."Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6".CHEMISTRY OF MATERIALS 21.13(2009):2846-2850.
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