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学科主题: Chemistry
题名: Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O
作者: Wang Yongjiang; Pan Shilie; Tian Xuelin; Zhou Zhongxiang; Liu Gang; Wang Jide; Jia Dianzeng
刊名: INORGANIC CHEMISTRY
发表日期: 2009
DOI: 10.1021/ic900700u
卷: 48, 期:16, 页:7800-7804
收录类别: SCI
英文摘要: Single crystal of hydrated sodium borate Na2B5O8(OH)center dot 2H(2)O has been grown with sizes up to 5 x 5 x 3 mm(3) under mild hydrothermal conditions at 180 degrees C. The structure is determined by single-crystal X-ray diffraction and further characterized by IR and TG analyses. It crystallizes in the orthorhombic space group Pna2(1), with a = 11.967(2) angstrom, b = 6.5320(13) angstrom, c = 11.126(2) angstrom, Z = 4, R1 = 0.0183, and wR2 = 0.0483. The crystal structure of Na2B5O8(OH)center dot 2H(2)O is made up of Na-O polyhedra, and B5O8(OH)(2-) polyborate anions. Transmittance spectrum is performed on the Na2B5O8(OH)center dot 2H(2)O crystal, which shows an absorption edge less than 190 nm in the UV region. The powder second-harmonic generation intensity measured by the Kurtz-Perry method indicates that Na2B5O8 center dot(OH)center dot 2H(2)O is about half that of KH2PO4 (KDP).
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1880
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China

Recommended Citation:
Wang Yongjiang,Pan Shilie,Tian Xuelin,et al. Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O[J]. INORGANIC CHEMISTRY,2009,48(16):7800-7804.
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文件名: synthesis, structure, and properties of the noncentrosymmetric hydrated borate na2b5o8(oh)center dot 2h(2)o.pdf
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