Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O
Wang Yongjiang; Pan Shilie; Tian Xuelin; Zhou Zhongxiang; Liu Gang; Wang Jide; Jia Dianzeng
2009
发表期刊INORGANIC CHEMISTRY
ISSN0020-1669
卷号48期号:16页码:7800-7804
摘要

Single crystal of hydrated sodium borate Na2B5O8(OH)center dot 2H(2)O has been grown with sizes up to 5 x 5 x 3 mm(3) under mild hydrothermal conditions at 180 degrees C. The structure is determined by single-crystal X-ray diffraction and further characterized by IR and TG analyses. It crystallizes in the orthorhombic space group Pna2(1), with a = 11.967(2) angstrom, b = 6.5320(13) angstrom, c = 11.126(2) angstrom, Z = 4, R1 = 0.0183, and wR2 = 0.0483. The crystal structure of Na2B5O8(OH)center dot 2H(2)O is made up of Na-O polyhedra, and B5O8(OH)(2-) polyborate anions. Transmittance spectrum is performed on the Na2B5O8(OH)center dot 2H(2)O crystal, which shows an absorption edge less than 190 nm in the UV region. The powder second-harmonic generation intensity measured by the Kurtz-Perry method indicates that Na2B5O8 center dot(OH)center dot 2H(2)O is about half that of KH2PO4 (KDP).

学科领域Chemistry
DOI10.1021/ic900700u
收录类别SCI
WOS记录号WOS:000268661500039
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被引频次:58[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1880
专题新疆维吾尔自治区电子信息材料与器件重点实验室
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
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Wang Yongjiang,Pan Shilie,Tian Xuelin,et al. Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O[J]. INORGANIC CHEMISTRY,2009,48(16):7800-7804.
APA Wang Yongjiang.,Pan Shilie.,Tian Xuelin.,Zhou Zhongxiang.,Liu Gang.,...&Jia Dianzeng.(2009).Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O.INORGANIC CHEMISTRY,48(16),7800-7804.
MLA Wang Yongjiang,et al."Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O".INORGANIC CHEMISTRY 48.16(2009):7800-7804.
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