Growth and Properties of Single Crystals of Noncentrosymmetric Na3VO2B6O11
Fan Xiaoyun; Pan Shilie; Hou Xueling; Tian Xuelin; Han Jian; Haag Jacob; Poeppelmeier Kenneth R.
2010
发表期刊CRYSTAL GROWTH & DESIGN
ISSN1528-7483
卷号10期号:1页码:252-256
摘要

A new nonlinear optical crystal, Na3VO2B6O11, hit s been grown by the top-seeded sol Lit ion growl h method using it Na2CO3V2O5 flux. The structure of the compound was determined by single-crystal X-ray diffraction. It crystallizes in the noncentrosymmetric orthorhombic system, space group P2(1)2(1)2(1), with cell parameters a = 7.7359(9) angstrom, h = 10. 1884(12) angstrom, c = 12.5697(15) angstrom, V = 990.7(2) angstrom(3), and Z = 4. Na3VO2B6O11 has, a three-dimensional structure consisting of hexaborate groups connected by VO4 tetrahedra with the sodium atoms distributed in channels through Out the three-dimensional network. The refractive indices have been measured by the minimum deviation technique and fit to the Sellmeier equations. Nonlinearoptical Measurements on the compound demonstrate that the material has second harmonic generation properties, with an efficiency approximately the same as that of KH2BO4.

学科领域Chemistry ; Crystallography ; Materials Science
DOI10.1021/cg900877h
收录类别SCI
WOS记录号WOS:000274757100040
引用统计
被引频次:64[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1872
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
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Fan Xiaoyun,Pan Shilie,Hou Xueling,et al. Growth and Properties of Single Crystals of Noncentrosymmetric Na3VO2B6O11[J]. CRYSTAL GROWTH & DESIGN,2010,10(1):252-256.
APA Fan Xiaoyun.,Pan Shilie.,Hou Xueling.,Tian Xuelin.,Han Jian.,...&Poeppelmeier Kenneth R..(2010).Growth and Properties of Single Crystals of Noncentrosymmetric Na3VO2B6O11.CRYSTAL GROWTH & DESIGN,10(1),252-256.
MLA Fan Xiaoyun,et al."Growth and Properties of Single Crystals of Noncentrosymmetric Na3VO2B6O11".CRYSTAL GROWTH & DESIGN 10.1(2010):252-256.
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