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学科主题: Chemistry ; Crystallography ; Materials Science
题名: growth and properties of single crystals of noncentrosymmetric na3vo2b6o11
作者: Fan Xiaoyun; Pan Shilie; Hou Xueling; Tian Xuelin; Han Jian; Haag Jacob; Poeppelmeier Kenneth R.
刊名: CRYSTAL GROWTH & DESIGN
发表日期: 2010
DOI: 10.1021/cg900877h
卷: 10, 期:1, 页:252-256
收录类别: SCI
摘要: A new nonlinear optical crystal, Na3VO2B6O11, hit s been grown by the top-seeded sol Lit ion growl h method using it Na2CO3V2O5 flux. The structure of the compound was determined by single-crystal X-ray diffraction. It crystallizes in the noncentrosymmetric orthorhombic system, space group P2(1)2(1)2(1), with cell parameters a = 7.7359(9) angstrom, h = 10. 1884(12) angstrom, c = 12.5697(15) angstrom, V = 990.7(2) angstrom(3), and Z = 4. Na3VO2B6O11 has, a three-dimensional structure consisting of hexaborate groups connected by VO4 tetrahedra with the sodium atoms distributed in channels through Out the three-dimensional network. The refractive indices have been measured by the minimum deviation technique and fit to the Sellmeier equations. Nonlinearoptical Measurements on the compound demonstrate that the material has second harmonic generation properties, with an efficiency approximately the same as that of KH2BO4.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1872
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

Recommended Citation:
Fan Xiaoyun,Pan Shilie,Hou Xueling,et al. growth and properties of single crystals of noncentrosymmetric na3vo2b6o11[J]. CRYSTAL GROWTH & DESIGN,2010,10(1):252-256.
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文件名: growth and properties of single crystals of noncentrosymmetric na3vo2b6o11.pdf
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