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学科主题: Chemistry ; Physics
题名: Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H10
作者: Wang Yongjiang; Pan Shilie; Hou Xueling; Liu Gang; Wang Jide; Jia Dianzeng
通讯作者: Pan, SL
刊名: Solid State Sciences
发表日期: 2010
DOI: 10.1016/j.solidstatesciences.2010.07.021
卷: 12, 期:10, 页:1726-1730
摘要: In this study, both solvent evaporation and hydrothermal methods were employed to grow hydrated sodium borate crystals using NaOH and H 3BO3 as reagents, and transparent and colorless single-crystals were successfully obtained with sizes up to 12 × 6 × 6 mm3 and 6 × 5 × 4 mm3, respectively. The structure is determined by single-crystal X-ray diffraction techniques. The title compound crystallizes in the trigonal space group R32, with a = 11.1042(16) , b = 11.1042(16) , c = 21.131(4) , Z = 9 and R1 = 0.0322, wR2 = 0.0840. Infrared and transmission spectra are presented for the reported material. The powder second-harmonic generation (SHG) intensity measured by the Kurtz-Perry method indicates that the SHG effect of Na2B4O12H10 is about one-third times that of KH2PO4 (KDP). © 2010 Elsevier Masson SAS. All rights reserved.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1853
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China

Recommended Citation:
Wang Yongjiang,Pan Shilie,Hou Xueling,et al. Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H10[J]. Solid State Sciences,2010,12(10):1726-1730.
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