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水相中β-环糊精包合N-羟基邻苯二甲酰亚胺作用研究
Alternative Titlestudy on inclusion between beta-cyclodextrin and nhpi in aqueous solution
贺永桓; 文彬; 高林; 杨丹红
2011
Source Publication应用化工
ISSN1671-3206
Volume40Issue:6Pages:1055-1058
Abstract研究了水相中beta-环糊精与N-羟基邻苯二甲酰亚胺(NHPI)的包合作用,通过Hildebrand-Benesi法确定其包合比为1∶1,并结合 红外光谱辅助说明,同时计算出25℃时包合稳定常数为1 412 L/mo,l计算出热力学常数DeltaH、DeltaS、DeltaG,初步探讨了超声波对包结产率的影响规律。
Other AbstractThe study on inclusion between beta-cyclodextrin and NHPI in aqueous solution has been made.The ratio of inclusion 1:1 was calculated by the method of Hildebrand-Benesi ,which was tested by IR.The inclusion constant was also calculated,which was 1 412 L/mol.The thermodynamic parameters for inclusion reaction such as △H,△S,△G were derived from the inclusion constants at different temperatures.We have a simple description on the inclusion yield under the supersonic condition.
KeywordN-羟基邻苯二甲酰亚胺 Β-环糊精 包合 包合常数
Subject AreaChemistry (Provided By Thomson Reuters)
DOI10.16581/j.cnki.issn1671-3206.2011.06.035
Indexed ByCSCD
CSCD IDCSCD:4241250
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1842
Collection资源化学研究室
Affiliation中国科学院新疆理化技术研究所;中国科学院研究生院
Recommended Citation
GB/T 7714
贺永桓,文彬,高林,等. 水相中β-环糊精包合N-羟基邻苯二甲酰亚胺作用研究[J]. 应用化工,2011,40(6):1055-1058.
APA 贺永桓,文彬,高林,&杨丹红.(2011).水相中β-环糊精包合N-羟基邻苯二甲酰亚胺作用研究.应用化工,40(6),1055-1058.
MLA 贺永桓,et al."水相中β-环糊精包合N-羟基邻苯二甲酰亚胺作用研究".应用化工 40.6(2011):1055-1058.
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