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Solid-State Photochromic Properties and Mechanism of 1-Phenyl-3-methyl-4-(3-chlorobenzal)-5-hydroxypyrazole 4-Methylthiosemicarbazone
Guo Jixi; Liu Lang; Jia Dianzeng; Wang Junhua; Xie Xiaolin
2009
Source PublicationJournal of Physical Chemistry A
ISSN10895639
Volume113Issue:7Pages:1255-1258
Abstract4-Acylhydroxypyrazoles combined with thiosemicarbazide derivants exhibit excellent photochromism in the crystalline state. Upon irradiation with 365 nm light, colorless enol-form isomers are converted to the yellow keto-form isomers. FT-IR, UV/vis, and fluorescence spectra were used to investigate the photochromic behavior of l-phenyl-3-methyl-4-(3-chlorobenzal)-5-hydroxypyrazole 4-methylthiosemicarbazone. A possible photo-chromic mechanism has been proposed based on the analysis of the crystal structure of the sample.
Subject AreaChemistry ; Physics
DOI10.1021/jp808378e
WOS IDWOS:000263268200012
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Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1830
Collection材料物理与化学研究室
AffiliationXinjiang Univ, Inst Appl Chem, Urumqi 830046, Xinjiang, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Xinjiang, Peoples R China;Huazhong Univ Sci & Technol, Natl Anticounterfeit Engn Res Ctr, Dept Chem & Chem Engn, Wuhan 430074, Peoples R China
Recommended Citation
GB/T 7714
Guo Jixi,Liu Lang,Jia Dianzeng,et al. Solid-State Photochromic Properties and Mechanism of 1-Phenyl-3-methyl-4-(3-chlorobenzal)-5-hydroxypyrazole 4-Methylthiosemicarbazone[J]. Journal of Physical Chemistry A,2009,113(7):1255-1258.
APA Guo Jixi,Liu Lang,Jia Dianzeng,Wang Junhua,&Xie Xiaolin.(2009).Solid-State Photochromic Properties and Mechanism of 1-Phenyl-3-methyl-4-(3-chlorobenzal)-5-hydroxypyrazole 4-Methylthiosemicarbazone.Journal of Physical Chemistry A,113(7),1255-1258.
MLA Guo Jixi,et al."Solid-State Photochromic Properties and Mechanism of 1-Phenyl-3-methyl-4-(3-chlorobenzal)-5-hydroxypyrazole 4-Methylthiosemicarbazone".Journal of Physical Chemistry A 113.7(2009):1255-1258.
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