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学科主题: Chemistry
题名: syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines
作者: Yang Yun; Pan Shilie; Hou Xueling; Guo Jing; Li Feng; Han Jian; Guo Jixi; Jia Dianzeng
通讯作者: Pan, SL
关键词: Salicylic acid ; Borate ; Organic amino ; Crystal structures ; Fluorescence
刊名: INORGANICA CHIMICA ACTA
发表日期: 2011
DOI: 10.1016/j.ica.2010.06.010
卷: 365, 期:1, 页:20-24
收录类别: SCI
资助者: National Natural Science Foundation of China 50802110; "One Hundred Talents Project Foundation Program" of Chinese Academe of Sciences; "Western Light Joint Scholar Foundation" Program of Chinese Academe of Sciences; Scientific Research Foundation for the Returned Overseas Chinese Scholars; State Education Ministry 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; Xinjiang Uygur Autonomous
摘要: Three new borates containing nonmetal compounds, C(4)H(12)NBO(4)(C(7)H4(O))(2) (1), C(8)H(20)NBO(4)(C(7)H(4)O)2 (2) and C(6)H(18)N(2)(0.5)BO(4)(C(7)H(4)O)(2) (3) have been prepared, aiming at the formation of extended supramolecular networks with organic-inorganic hybrid materials of salicylic acid and boric acid. The corresponding compounds have been characterized by chemical and spectroscopic techniques. X-ray diffraction analyses of available single crystals revealed that the molecular structures of the three compounds have the same isolated BO(4)(C(7)H(4)O)(2) anion. The BO(4)(C(7)H(4)O)(2) anion with a distorted BO(4) tetrahedron is formed by bidentate coordination of the B atom to two salicylic acid molecules via the O atoms of the central carboxyl and alpha-hydroxyl groups. The three compounds display violet luminescence with emission maxima around 365 nm.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1675
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China; Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China

Recommended Citation:
Yang Yun,Pan Shilie,Hou Xueling,et al. syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines[J]. INORGANICA CHIMICA ACTA,2011,365(1):20-24.
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