syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines
Yang Yun; Pan Shilie; Hou Xueling; Guo Jing; Li Feng; Han Jian; Guo Jixi; Jia Dianzeng
2011
Source PublicationINORGANICA CHIMICA ACTA
ISSN0020-1693
Volume365Issue:1Pages:20-24
Abstract

Three new borates containing nonmetal compounds, [C(4)H(12)N][BO(4)(C(7)H4(O))(2)] (1), [C(8)H(20)N][BO(4)(C(7)H(4)O)2] (2) and [C(6)H(18)N(2)](0.5)[BO(4)(C(7)H(4)O)(2)] (3) have been prepared, aiming at the formation of extended supramolecular networks with organic-inorganic hybrid materials of salicylic acid and boric acid. The corresponding compounds have been characterized by chemical and spectroscopic techniques. X-ray diffraction analyses of available single crystals revealed that the molecular structures of the three compounds have the same isolated [BO(4)(C(7)H(4)O)(2)] anion. The [BO(4)(C(7)H(4)O)(2)] anion with a distorted BO(4) tetrahedron is formed by bidentate coordination of the B atom to two salicylic acid molecules via the O atoms of the central carboxyl and alpha-hydroxyl groups. The three compounds display violet luminescence with emission maxima around 365 nm.

KeywordSalicylic Acid Borate Organic Amino Crystal Structures Fluorescence
Subject AreaChemistry
DOI10.1016/j.ica.2010.06.010
Indexed BySCI
WOS IDWOS:000285624200003
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1675
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan Shilie
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
Recommended Citation
GB/T 7714
Yang Yun,Pan Shilie,Hou Xueling,et al. syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines[J]. INORGANICA CHIMICA ACTA,2011,365(1):20-24.
APA Yang Yun.,Pan Shilie.,Hou Xueling.,Guo Jing.,Li Feng.,...&Jia Dianzeng.(2011).syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines.INORGANICA CHIMICA ACTA,365(1),20-24.
MLA Yang Yun,et al."syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines".INORGANICA CHIMICA ACTA 365.1(2011):20-24.
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