Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties
Yang Yun; Pan Shilie; Li Hongyi; Han Jian; Chen Zhaohui; Zhao Wenwu; Zhou Zhongdang; Pan, SL
2011
发表期刊INORGANIC CHEMISTRY
ISSN0020-1669
卷号50期号:6页码:2415-2419
摘要

A new noncentrosymmetric polyborate, Li4Cs3B7O14, has been synthesized using the conventional solid state reaction method. It crystallizes in the trigonal space group P3(1)21 (No. 152) with unit cell parameters of a = 6.9313(6) angstrom, c = 26.799(3) angstrom, and Z = 3. The new structure contains an infinite three-dimensional matrix that is built from B7O14 building blocks rarely found in anhydrous borate compounds and LiOn (n = 4, 5), CsOn (n = 9, 10) polyhedra. The optical characterization of the compound indicates that the compound is phase matchable, and the UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material.

学科领域Chemistry
DOI10.1021/ic102214q
收录类别SCI
WOS记录号WOS:000288182700052
引用统计
被引频次:60[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1668
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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Yang Yun,Pan Shilie,Li Hongyi,et al. Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties[J]. INORGANIC CHEMISTRY,2011,50(6):2415-2419.
APA Yang Yun.,Pan Shilie.,Li Hongyi.,Han Jian.,Chen Zhaohui.,...&Pan, SL.(2011).Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties.INORGANIC CHEMISTRY,50(6),2415-2419.
MLA Yang Yun,et al."Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties".INORGANIC CHEMISTRY 50.6(2011):2415-2419.
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