Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties
Yang Yun; Pan Shilie; Li Hongyi; Han Jian; Chen Zhaohui; Zhao Wenwu; Zhou Zhongdang
2011
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume50Issue:6Pages:2415-2419
Abstract

A new noncentrosymmetric polyborate, Li4Cs3B7O14, has been synthesized using the conventional solid state reaction method. It crystallizes in the trigonal space group P3(1)21 (No. 152) with unit cell parameters of a = 6.9313(6) angstrom, c = 26.799(3) angstrom, and Z = 3. The new structure contains an infinite three-dimensional matrix that is built from B7O14 building blocks rarely found in anhydrous borate compounds and LiOn (n = 4, 5), CsOn (n = 9, 10) polyhedra. The optical characterization of the compound indicates that the compound is phase matchable, and the UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material.

Subject AreaChemistry
DOI10.1021/ic102214q
Indexed BySCI
WOS IDWOS:000288182700052
Citation statistics
Cited Times:66[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1668
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Yang Yun,Pan Shilie,Li Hongyi,et al. Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties[J]. INORGANIC CHEMISTRY,2011,50(6):2415-2419.
APA Yang Yun.,Pan Shilie.,Li Hongyi.,Han Jian.,Chen Zhaohui.,...&Zhou Zhongdang.(2011).Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties.INORGANIC CHEMISTRY,50(6),2415-2419.
MLA Yang Yun,et al."Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties".INORGANIC CHEMISTRY 50.6(2011):2415-2419.
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