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学科主题: Chemistry ; Crystallography
题名: Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br
作者: Zhang Min; Pan Shi-Lie; Fan Xiao-Yun; Zhou Zhong-Xiang; Poeppelmeier Kenneth R.; Yang Yun
通讯作者: Pan, SL
刊名: CRYSTENGCOMM
发表日期: 2011
DOI: 10.1039/c0ce00725k
卷: 13, 期:8, 页:2899-2903
收录类别: SCI
摘要: A high quality single crystal of K3B6O10Br has been grown with sizes up to 14 x 12 x 7 mm(3) by the top-seeded solution growth method. It crystallizes in a noncentrosymetric trigonal system, space group R3m with cell parameters a = 10.1153(8)angstrom, c = 8.8592(14)angstrom, Z = 3, V = 785.02(15)angstrom(3). K3B6O10Br has a three-dimensional network consisting of B6O13 units, which are surrounded by a K-Br framework. A transmission spectrum of the K3B6O10Br crystal was reported. Its refractive indices were measured by a minimum deviation technique and fit to Sellmeier equations. Nonlinear optical measurements demonstrate that the material has second harmonic generation properties, with efficiency approximately three times that of KH2PO4.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1666
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

Recommended Citation:
Zhang Min,Pan Shi-Lie,Fan Xiao-Yun,et al. Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br[J]. CRYSTENGCOMM,2011,13(8):2899-2903.
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文件名: crystal growth and optical properties of a noncentrosymmetric haloid borate, k3b6o10br.pdf
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