Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br
Zhang Min; Pan Shi-Lie; Fan Xiao-Yun; Zhou Zhong-Xiang; Poeppelmeier Kenneth R.; Yang Yun
2011
发表期刊CRYSTENGCOMM
ISSN1466-8033
卷号13期号:8页码:2899-2903
摘要

A high quality single crystal of K3B6O10Br has been grown with sizes up to 14 x 12 x 7 mm(3) by the top-seeded solution growth method. It crystallizes in a noncentrosymetric trigonal system, space group R3m with cell parameters a = 10.1153(8)angstrom, c = 8.8592(14)angstrom, Z = 3, V = 785.02(15)angstrom(3). K3B6O10Br has a three-dimensional network consisting of B6O13 units, which are surrounded by a K-Br framework. A transmission spectrum of the K3B6O10Br crystal was reported. Its refractive indices were measured by a minimum deviation technique and fit to Sellmeier equations. Nonlinear optical measurements demonstrate that the material has second harmonic generation properties, with efficiency approximately three times that of KH2PO4.

学科领域Chemistry ; Crystallography
DOI10.1039/c0ce00725k
收录类别SCI
WOS记录号WOS:000288905000013
引用统计
被引频次:61[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1666
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan Shi-Lie
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
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Zhang Min,Pan Shi-Lie,Fan Xiao-Yun,et al. Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br[J]. CRYSTENGCOMM,2011,13(8):2899-2903.
APA Zhang Min,Pan Shi-Lie,Fan Xiao-Yun,Zhou Zhong-Xiang,Poeppelmeier Kenneth R.,&Yang Yun.(2011).Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br.CRYSTENGCOMM,13(8),2899-2903.
MLA Zhang Min,et al."Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br".CRYSTENGCOMM 13.8(2011):2899-2903.
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