Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br
Zhang Min; Pan Shi-Lie; Fan Xiao-Yun; Zhou Zhong-Xiang; Poeppelmeier Kenneth R.; Yang Yun
2011
Source PublicationCRYSTENGCOMM
ISSN1466-8033
Volume13Issue:8Pages:2899-2903
Abstract

A high quality single crystal of K3B6O10Br has been grown with sizes up to 14 x 12 x 7 mm(3) by the top-seeded solution growth method. It crystallizes in a noncentrosymetric trigonal system, space group R3m with cell parameters a = 10.1153(8)angstrom, c = 8.8592(14)angstrom, Z = 3, V = 785.02(15)angstrom(3). K3B6O10Br has a three-dimensional network consisting of B6O13 units, which are surrounded by a K-Br framework. A transmission spectrum of the K3B6O10Br crystal was reported. Its refractive indices were measured by a minimum deviation technique and fit to Sellmeier equations. Nonlinear optical measurements demonstrate that the material has second harmonic generation properties, with efficiency approximately three times that of KH2PO4.

Subject AreaChemistry ; Crystallography
DOI10.1039/c0ce00725k
Indexed BySCI
WOS IDWOS:000288905000013
Citation statistics
Cited Times:63[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1666
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shi-Lie
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
Recommended Citation
GB/T 7714
Zhang Min,Pan Shi-Lie,Fan Xiao-Yun,et al. Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br[J]. CRYSTENGCOMM,2011,13(8):2899-2903.
APA Zhang Min,Pan Shi-Lie,Fan Xiao-Yun,Zhou Zhong-Xiang,Poeppelmeier Kenneth R.,&Yang Yun.(2011).Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br.CRYSTENGCOMM,13(8),2899-2903.
MLA Zhang Min,et al."Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br".CRYSTENGCOMM 13.8(2011):2899-2903.
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