Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit
Zhao Wenwu; Pan Shilie; Han Jian; Zhou Zhongxiang; Tian Xuelin; Li Junjie
2011
Source PublicationINORGANIC CHEMISTRY COMMUNICATIONS
ISSN1387-7003
Volume14Issue:4Pages:566-568
Abstract

Pb8B9O21F has been synthesized from the PbO-PbF2-B2O3 system for the first time. It crystallizes in the trigonal system, space group R-3c with unit-cell parameters a = 9.740(3)angstrom, b = 9.740(3)angstrom, c = 38.167(15)angstrom, Z = 6, and volume = 3135.5(8)angstrom(3). The structure of the compound is solved by the direct methods and to the best of our knowledge, Pb8B9O21F is the first structure reported so far with isolated boron-oxygen anionic [B9O21](15-) compound. Functional groups present in the sample were identified by Fourier transform infrared spectrum. The Diffuse reflectance spectrum shows that the ultraviolet cutoff edge for the Pb8B9O21F crystal is about 276 nm.

KeywordPb8b9o21f Synthesis Crystal Structure B9o21(15-) Unit
Subject AreaChemistry
DOI10.1016/j.inoche.2011.01.026
Indexed BySCI
WOS IDWOS:000289126500014
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1664
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2011,14(4):566-568.
APA Zhao Wenwu,Pan Shilie,Han Jian,Zhou Zhongxiang,Tian Xuelin,&Li Junjie.(2011).Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit.INORGANIC CHEMISTRY COMMUNICATIONS,14(4),566-568.
MLA Zhao Wenwu,et al."Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit".INORGANIC CHEMISTRY COMMUNICATIONS 14.4(2011):566-568.
Files in This Item:
File Name/Size DocType Version Access License
synthesis, crystal s(640KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhao Wenwu]'s Articles
[Pan Shilie]'s Articles
[Han Jian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhao Wenwu]'s Articles
[Pan Shilie]'s Articles
[Han Jian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhao Wenwu]'s Articles
[Pan Shilie]'s Articles
[Han Jian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated b9o21(15-) unit.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.