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学科主题: Chemistry
题名: Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit
作者: Zhao Wenwu; Pan Shilie; Han Jian; Zhou Zhongxiang; Tian Xuelin; Li Junjie
通讯作者: Pan, SL
关键词: Pb8B9O21F ; Synthesis ; Crystal structure ; B9O21(15-) unit
刊名: INORGANIC CHEMISTRY COMMUNICATIONS
发表日期: 2011
DOI: 10.1016/j.inoche.2011.01.026
卷: 14, 期:4, 页:566-568
收录类别: SCI
资助者: National Natural Science Foundation of China 50802110, 21001114; One Hundred Talents Project Foundation Program; Foundation of the Ministry of Education of China for Returned Scholars 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 200816120
摘要: Pb8B9O21F has been synthesized from the PbO-PbF2-B2O3 system for the first time. It crystallizes in the trigonal system, space group R-3c with unit-cell parameters a = 9.740(3)angstrom, b = 9.740(3)angstrom, c = 38.167(15)angstrom, Z = 6, and volume = 3135.5(8)angstrom(3). The structure of the compound is solved by the direct methods and to the best of our knowledge, Pb8B9O21F is the first structure reported so far with isolated boron-oxygen anionic B9O21(15-) compound. Functional groups present in the sample were identified by Fourier transform infrared spectrum. The Diffuse reflectance spectrum shows that the ultraviolet cutoff edge for the Pb8B9O21F crystal is about 276 nm.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1664
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2011,14(4):566-568.
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文件名: synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated b9o21(15-) unit.pdf
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