Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit
Zhao Wenwu; Pan Shilie; Han Jian; Zhou Zhongxiang; Tian Xuelin; Li Junjie; Pan, SL
2011
发表期刊INORGANIC CHEMISTRY COMMUNICATIONS
ISSN1387-7003
卷号14期号:4页码:566-568
摘要

Pb8B9O21F has been synthesized from the PbO-PbF2-B2O3 system for the first time. It crystallizes in the trigonal system, space group R-3c with unit-cell parameters a = 9.740(3)angstrom, b = 9.740(3)angstrom, c = 38.167(15)angstrom, Z = 6, and volume = 3135.5(8)angstrom(3). The structure of the compound is solved by the direct methods and to the best of our knowledge, Pb8B9O21F is the first structure reported so far with isolated boron-oxygen anionic [B9O21](15-) compound. Functional groups present in the sample were identified by Fourier transform infrared spectrum. The Diffuse reflectance spectrum shows that the ultraviolet cutoff edge for the Pb8B9O21F crystal is about 276 nm.

关键词Pb8b9o21f Synthesis Crystal Structure B9o21(15-) Unit
学科领域Chemistry
DOI10.1016/j.inoche.2011.01.026
收录类别SCI
WOS记录号WOS:000289126500014
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1664
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2011,14(4):566-568.
APA Zhao Wenwu.,Pan Shilie.,Han Jian.,Zhou Zhongxiang.,Tian Xuelin.,...&Pan, SL.(2011).Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit.INORGANIC CHEMISTRY COMMUNICATIONS,14(4),566-568.
MLA Zhao Wenwu,et al."Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21](15-) unit".INORGANIC CHEMISTRY COMMUNICATIONS 14.4(2011):566-568.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
synthesis, crystal s(640KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhao Wenwu]的文章
[Pan Shilie]的文章
[Han Jian]的文章
百度学术
百度学术中相似的文章
[Zhao Wenwu]的文章
[Pan Shilie]的文章
[Han Jian]的文章
必应学术
必应学术中相似的文章
[Zhao Wenwu]的文章
[Pan Shilie]的文章
[Han Jian]的文章
相关权益政策
暂无数据
收藏/分享
文件名: synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated b9o21(15-) unit.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。