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学科主题: Chemistry
题名: Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines
作者: Yao Ming; Lu Chong-Dao
通讯作者: Lu, CD
刊名: ORGANIC LETTERS
发表日期: 2011
DOI: 10.1021/ol201029b
卷: 13, 期:10, 页:2782-2785
收录类别: SCI
资助者: Chinese Academy of SciencesNational Natural Science Foundation of China
摘要: Three-component coupling reactions of sulfonylimidates, silyl glyoxylates and N-tert-butanesulfinyl aldimines efficiently provide cyclic N-sulfonylamiclines containing free endocyclic N-H. The formation of two C-C bonds (contiguous stereogenic carbons), one O-Si bond, and one C-N bond, together with the cleavage of the chiral auxiliary (tert-butanesulfinyl group), occurs with excellent chemoselectivity, diastereoselectivity, and enantioselectivity in this one-pot cascade transformation.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1661
Appears in Collections:资源化学研究室_期刊论文

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three component reactions of sulfonylimidates silyl glyoxylates and n-tert-butanesulfinyl aldimines an efficient diastereoselective and enantioselective synthesis of cyclic n sulfonylamidines.pdf(738KB)期刊论文作者接受稿开放获取View 联系获取全文

作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Urumqi 830011, Peoples R China

Recommended Citation:
Yao Ming,Lu Chong-Dao. Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines[J]. ORGANIC LETTERS,2011,13(10):2782-2785.
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文件名: three component reactions of sulfonylimidates silyl glyoxylates and n-tert-butanesulfinyl aldimines an efficient diastereoselective and enantioselective synthesis of cyclic n sulfonylamidines.pdf
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