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Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines
Yao Ming; Lu Chong-Dao; Lu, CD
2011
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume13Issue:10Pages:2782-2785
AbstractThree-component coupling reactions of sulfonylimidates, silyl glyoxylates and N-tert-butanesulfinyl aldimines efficiently provide cyclic N-sulfonylamiclines containing free endocyclic N-H. The formation of two C-C bonds (contiguous stereogenic carbons), one O-Si bond, and one C-N bond, together with the cleavage of the chiral auxiliary (tert-butanesulfinyl group), occurs with excellent chemoselectivity, diastereoselectivity, and enantioselectivity in this one-pot cascade transformation.
Subject AreaChemistry
DOI10.1021/ol201029b
Indexed BySCI
WOS IDWOS:000290465800069
Citation statistics
Cited Times:26[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1661
Collection资源化学研究室
Corresponding AuthorLu, CD
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Yao Ming,Lu Chong-Dao,Lu, CD. Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines[J]. ORGANIC LETTERS,2011,13(10):2782-2785.
APA Yao Ming,Lu Chong-Dao,&Lu, CD.(2011).Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines.ORGANIC LETTERS,13(10),2782-2785.
MLA Yao Ming,et al."Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines".ORGANIC LETTERS 13.10(2011):2782-2785.
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