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Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines
Yao Ming; Lu Chong-Dao; Lu, CD
2011
发表期刊ORGANIC LETTERS
ISSN1523-7060
卷号13期号:10页码:2782-2785
摘要Three-component coupling reactions of sulfonylimidates, silyl glyoxylates and N-tert-butanesulfinyl aldimines efficiently provide cyclic N-sulfonylamiclines containing free endocyclic N-H. The formation of two C-C bonds (contiguous stereogenic carbons), one O-Si bond, and one C-N bond, together with the cleavage of the chiral auxiliary (tert-butanesulfinyl group), occurs with excellent chemoselectivity, diastereoselectivity, and enantioselectivity in this one-pot cascade transformation.
学科领域Chemistry
DOI10.1021/ol201029b
收录类别SCI
WOS记录号WOS:000290465800069
引用统计
被引频次:25[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1661
专题资源化学研究室
通讯作者Lu, CD
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Urumqi 830011, Peoples R China
推荐引用方式
GB/T 7714
Yao Ming,Lu Chong-Dao,Lu, CD. Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines[J]. ORGANIC LETTERS,2011,13(10):2782-2785.
APA Yao Ming,Lu Chong-Dao,&Lu, CD.(2011).Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines.ORGANIC LETTERS,13(10),2782-2785.
MLA Yao Ming,et al."Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines".ORGANIC LETTERS 13.10(2011):2782-2785.
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