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学科主题: Chemistry
题名: Synthesis, crystal structure and optical properties of a new lead bismuth borate
作者: Zhao Wenwu; Pan Shilie; Han Jian; Zhou Zhongxiang
通讯作者: Pan, SL
关键词: PbBiBO(4) ; Powder synthesis ; Crystal structure ; UV-Vis-NIR Diffuse-Reflectance spectrum
刊名: INORGANICA CHIMICA ACTA
发表日期: 2011
DOI: 10.1016/j.ica.2011.09.057
卷: 379, 期:1, 页:130-134
收录类别: SCI
资助者: National Natural Science Foundation of China 50802110, 21001114; Chinese Academy of Sciences; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; Xinjiang Uygur Autonomous Region of China 200816120
摘要: A new phase of the compound PbBiBO(4) has been successfully synthesized via the standard solid-state reaction, and the crystal structure has been determined from X-ray monocrystal diffraction data. It crystallizes in orthorhombic space group Cmca (No. 64) with lattice constants a = 10.782(3) angstrom, b = 10.502(3) angstrom, c = 7.477(2) angstrom, Z = 8. The crystal structure is characterized by a three-dimensional structure consisting of BiO(6) octahedra, PbO(4) tetrahedra and BO(3) triangles. The BiO(6) octahedra compose the layers through the O(2) atoms and O(3) atoms along the 101 direction, which connects the BO(3) trigonal groups by sharing the O(3) and two O(1) atoms and links the PbO(4) tetrahedra through the O(2) atoms. The UV-Vis-NIR Diffuse-Reflectance spectrum shows that the ultraviolet cutoff edge for the PbBiBO(4) crystal is about 310 nm. Functional groups in the sample were identified by Infrared spectrum.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1650
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a new lead bismuth borate[J]. INORGANICA CHIMICA ACTA,2011,379(1):130-134.
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