Synthesis, crystal structure and optical properties of a new lead bismuth borate
Zhao Wenwu; Pan Shilie; Han Jian; Zhou Zhongxiang
2011
Source PublicationINORGANICA CHIMICA ACTA
ISSN0020-1693
Volume379Issue:1Pages:130-134
Abstract

A new phase of the compound PbBiBO(4) has been successfully synthesized via the standard solid-state reaction, and the crystal structure has been determined from X-ray monocrystal diffraction data. It crystallizes in orthorhombic space group Cmca (No. 64) with lattice constants a = 10.782(3) angstrom, b = 10.502(3) angstrom, c = 7.477(2) angstrom, Z = 8. The crystal structure is characterized by a three-dimensional structure consisting of BiO(6) octahedra, PbO(4) tetrahedra and BO(3) triangles. The BiO(6) octahedra compose the layers through the O(2) atoms and O(3) atoms along the [101] direction, which connects the BO(3) trigonal groups by sharing the O(3) and two O(1) atoms and links the PbO(4) tetrahedra through the O(2) atoms. The UV-Vis-NIR Diffuse-Reflectance spectrum shows that the ultraviolet cutoff edge for the PbBiBO(4) crystal is about 310 nm. Functional groups in the sample were identified by Infrared spectrum.

KeywordPbbibo(4) Powder Synthesis Crystal Structure Uv-vis-nir Diffuse-reflectance Spectrum
Subject AreaChemistry
DOI10.1016/j.ica.2011.09.057
Indexed BySCI
WOS IDWOS:000297266200020
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1650
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a new lead bismuth borate[J]. INORGANICA CHIMICA ACTA,2011,379(1):130-134.
APA Zhao Wenwu,Pan Shilie,Han Jian,&Zhou Zhongxiang.(2011).Synthesis, crystal structure and optical properties of a new lead bismuth borate.INORGANICA CHIMICA ACTA,379(1),130-134.
MLA Zhao Wenwu,et al."Synthesis, crystal structure and optical properties of a new lead bismuth borate".INORGANICA CHIMICA ACTA 379.1(2011):130-134.
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