Synthesis, crystal structure and optical properties of a new lead bismuth borate
Zhao Wenwu; Pan Shilie; Han Jian; Zhou Zhongxiang
2011
发表期刊INORGANICA CHIMICA ACTA
ISSN0020-1693
卷号379期号:1页码:130-134
摘要

A new phase of the compound PbBiBO(4) has been successfully synthesized via the standard solid-state reaction, and the crystal structure has been determined from X-ray monocrystal diffraction data. It crystallizes in orthorhombic space group Cmca (No. 64) with lattice constants a = 10.782(3) angstrom, b = 10.502(3) angstrom, c = 7.477(2) angstrom, Z = 8. The crystal structure is characterized by a three-dimensional structure consisting of BiO(6) octahedra, PbO(4) tetrahedra and BO(3) triangles. The BiO(6) octahedra compose the layers through the O(2) atoms and O(3) atoms along the [101] direction, which connects the BO(3) trigonal groups by sharing the O(3) and two O(1) atoms and links the PbO(4) tetrahedra through the O(2) atoms. The UV-Vis-NIR Diffuse-Reflectance spectrum shows that the ultraviolet cutoff edge for the PbBiBO(4) crystal is about 310 nm. Functional groups in the sample were identified by Infrared spectrum.

关键词Pbbibo(4) Powder Synthesis Crystal Structure Uv-vis-nir Diffuse-reflectance Spectrum
学科领域Chemistry
DOI10.1016/j.ica.2011.09.057
收录类别SCI
WOS记录号WOS:000297266200020
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1650
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a new lead bismuth borate[J]. INORGANICA CHIMICA ACTA,2011,379(1):130-134.
APA Zhao Wenwu,Pan Shilie,Han Jian,&Zhou Zhongxiang.(2011).Synthesis, crystal structure and optical properties of a new lead bismuth borate.INORGANICA CHIMICA ACTA,379(1),130-134.
MLA Zhao Wenwu,et al."Synthesis, crystal structure and optical properties of a new lead bismuth borate".INORGANICA CHIMICA ACTA 379.1(2011):130-134.
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