中国科学院新疆理化技术研究所机构知识库
Advanced  
XJIPC OpenIR  > 新疆维吾尔自治区电子信息材料与器件重点实验室  > 期刊论文
学科主题: Chemistry ; Crystallography
题名: Li5Rb2B7O14: a new congruently melting compound with two kinds of B-O one-dimensional chains and short UV absorption edge
作者: Yang Yun; Pan Shilie; Hou Xueling; Dong Xiaoyu; Su Xin; Yang Zhihua; Zhang Min; Zhao Wenwu; Chen Zhaohui
通讯作者: Pan, SL
刊名: CRYSTENGCOMM
发表日期: 2012
DOI: 10.1039/c2ce06742k
卷: 14, 期:20, 页:6720-6725
收录类别: SCI
摘要: A new non-centrosymmetric polyborate, Li5Rb2B7O14, has been synthesized. The structure of the title compound was solved by single-crystal X-ray diffraction analysis. The infinite three-dimensional structure of Li5Rb2B7O14 is constructed from bridged LiOn (n = 4, 5, 6) and RbO10 polyhedra with two kinds of one-dimensional B-O chain fundamental building blocks through their vertex oxygen atoms. It melts congruently and exhibits a short-wavelength absorption onset at 190 nm. The feature of a short UV cut off edge is favourable in practical applications. The calculated band structure and the density of states of Li5Rb2B7O14 suggest that its indirect energy gap is 4.247 eV. The materials have also been characterized by infrared spectroscopy and thermal analysis.
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1647
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

Files in This Item:
File Name/ File Size Content Type Version Access License
li5rb2b7o14 a new congruently melting compound with two kinds of b-o one-dimensional chains and short uv absorption edge.pdf(553KB)期刊论文作者接受稿开放获取View 联系获取全文

作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Yang Yun,Pan Shilie,Hou Xueling,et al. Li5Rb2B7O14: a new congruently melting compound with two kinds of B-O one-dimensional chains and short UV absorption edge[J]. CRYSTENGCOMM,2012,14(20):6720-6725.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Yang Yun]'s Articles
[Pan Shilie]'s Articles
[Hou Xueling]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Yang Yun]‘s Articles
[Pan Shilie]‘s Articles
[Hou Xueling]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: li5rb2b7o14 a new congruently melting compound with two kinds of b-o one-dimensional chains and short uv absorption edge.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace