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学科主题: Chemistry
题名: UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units
作者: Wang Li; Pan Shilie; Chang Lixian; Hu Jianyang; Yu Hongwei
通讯作者: Pan, SL
刊名: INORGANIC CHEMISTRY
发表日期: 2012
DOI: 10.1021/ic2021337
卷: 51, 期:3, 页:1852-1858
收录类别: SCI
资助者: Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114, 21065012; Western Light Joint Scholar Foundation; Xinjiang Uygur Autonomous Region of China 201116143; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; Scientific Research Program of Urumqi of China G09212001; Science and Technology in Support of Xinjiang 201091244
摘要: A new noncentrosymmetric polyborate, Ba-2[B6O9(OH)(4)], has been synthesized under a hydrothermal condition. The polyborate contains chiral layers constructed by two kinds of helical chains and also form new B18O42 circles based on B3O8 units [(3: Delta+2T)]. One kind of Ba atom locates in the cavity surrounded by the B11O11 ring within the anion layer, and the other kind of Ba atom inserts between two adjacent layers. UV-vis diffuse reflectance spectroscopy demonstrates that the compound has a cutoff edge below 190 nm and has a large second-harmonic generation (SHG) effect, which is approximately 3 times that of KH2PO4 (KDP) and is type-I phase matchable
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1638
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Xinjiang Normal Univ, Coll Chem & Chem Engn, Urumqi 830054, Peoples R China

Recommended Citation:
Wang Li,Pan Shilie,Chang Lixian,et al. UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units[J]. INORGANIC CHEMISTRY,2012,51(3):1852-1858.
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文件名: UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units.pdf
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