UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units
Wang Li; Pan Shilie; Chang Lixian; Hu Jianyang; Yu Hongwei; Pan, SL
2012
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume51Issue:3Pages:1852-1858
Abstract

A new noncentrosymmetric polyborate, Ba-2[B6O9(OH)(4)], has been synthesized under a hydrothermal condition. The polyborate contains chiral layers constructed by two kinds of helical chains and also form new B18O42 circles based on B3O8 units [(3: Delta+2T)]. One kind of Ba atom locates in the cavity surrounded by the B11O11 ring within the anion layer, and the other kind of Ba atom inserts between two adjacent layers. UV-vis diffuse reflectance spectroscopy demonstrates that the compound has a cutoff edge below 190 nm and has a large second-harmonic generation (SHG) effect, which is approximately 3 times that of KH2PO4 (KDP) and is type-I phase matchable.

Subject AreaChemistry
DOI10.1021/ic2021337
Indexed BySCI
WOS IDWOS:000300474700078
Citation statistics
Cited Times:70[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1638
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan, SL
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Xinjiang Normal Univ, Coll Chem & Chem Engn, Urumqi 830054, Peoples R China
Recommended Citation
GB/T 7714
Wang Li,Pan Shilie,Chang Lixian,et al. UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units[J]. INORGANIC CHEMISTRY,2012,51(3):1852-1858.
APA Wang Li,Pan Shilie,Chang Lixian,Hu Jianyang,Yu Hongwei,&Pan, SL.(2012).UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units.INORGANIC CHEMISTRY,51(3),1852-1858.
MLA Wang Li,et al."UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units".INORGANIC CHEMISTRY 51.3(2012):1852-1858.
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