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学科主题: Chemistry
题名: New Borate-citrate: Synthesis, Structure, and Properties of Sr[B(C6H5O7)(2)](H2O)(4)center dot 3H(2)O
作者: Wu Hongping; Pan Shilie; Jia Dianzeng; Yu Hongwei; Chen Zhaohui
通讯作者: Pan, SL
关键词: SrB(C6H5O7)2(H2O)4 center dot 3H2O ; Single crystal growth ; X-ray diffraction ; Optical properties
刊名: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
发表日期: 2012
DOI: 10.1002/zaac.201100510
卷: 638, 期:5, 页:856-860
收录类别: SCI
资助者: Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114, 21065012; One Hundred Talents Project Foundation of Chinese Academy of Sciences; Western Light Joint Scholar Foundation of Chinese Academy of Sciences; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33, 200821166; Scientific Research Program of Urumqi of China G09212001; Science and Technology in Support of Xinjiang 201091244
摘要: Single crystals of SrB(C6H5O7)2(H2O)4.3H2O, a new borate-citrate material, were grown with sizes up to 8X6X2 mm by slow evaporation of water at room temperature. The structure of SrB(C6H5O7)2(H2O)(4).3H2O was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/c, with a = 11.363(3) angstrom, b = 18.829(4) angstrom, c = 11.976(3) angstrom, beta = 110.736(3)degrees, and Z = 4. The SrO8 dodecahedra, BO4 tetrahedra and citrate groups are linked together to form chains. The compound was characterized by IR and UV/Vis/NIR transmittance spectroscopy as well as thermal analysis.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1632
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China

Recommended Citation:
Wu Hongping,Pan Shilie,Jia Dianzeng,et al. New Borate-citrate: Synthesis, Structure, and Properties of Sr[B(C6H5O7)(2)](H2O)(4)center dot 3H(2)O[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2012,638(5):856-860.
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文件名: new boratecitrate synthesis, structure, and properties of srb(c6h5o7)(2)(h2o)(4)center dot 3h(2)o.pdf
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