Synthesis, structure characterization and optical properties of a new lead cadmium borate
Yu Hongwei; Pan Shilie; Wu Hongping; Han Jian; Li Hongyi; Yang Zhihua
2012
发表期刊INORGANICA CHIMICA ACTA
ISSN0020-1693
卷号384期号:4页码:158-162
摘要

A new ternary borate, Pb3Cd3(BO3)(4), has been synthesized by solid-state reaction at 530 degrees C. The compound crystallizes in the hexagonal space group P6(3)/m with a = 9.946(4), c = 7.003(5) angstrom, and Z = 2. The crystal structure consists of one-dimensional (1D) long [PbO5](infinity) tubes. The tubes are further connected by BO3 to generate a three-dimensional framework with the six-member tunnels along the c axis, where Cd atoms locate and the CdO6 octahedra form 1D chain. The IR spectrum confirms the presence of BO3 unit. The UV-Vis-IR diffuse reflectance spectrum exhibits a band gap of about 3.56 eV. The DSC analysis suggests that Pb3Cd3(BO3)(4) is an incongruent melting compound.

关键词Pb3cd3(Bo3)(4) Borate Synthesis Crystal Structure Optical Property
学科领域Chemistry
DOI10.1016/j.ica.2011.11.059
收录类别SCI
WOS记录号WOS:000301179600023
引用统计
被引频次:21[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1631
专题新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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Yu Hongwei,Pan Shilie,Wu Hongping,et al. Synthesis, structure characterization and optical properties of a new lead cadmium borate[J]. INORGANICA CHIMICA ACTA,2012,384(4):158-162.
APA Yu Hongwei,Pan Shilie,Wu Hongping,Han Jian,Li Hongyi,&Yang Zhihua.(2012).Synthesis, structure characterization and optical properties of a new lead cadmium borate.INORGANICA CHIMICA ACTA,384(4),158-162.
MLA Yu Hongwei,et al."Synthesis, structure characterization and optical properties of a new lead cadmium borate".INORGANICA CHIMICA ACTA 384.4(2012):158-162.
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