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学科主题: Chemistry
题名: Synthesis, structure characterization and optical properties of a new lead cadmium borate
作者: Yu Hongwei; Pan Shilie; Wu Hongping; Han Jian; Li Hongyi; Yang Zhihua
通讯作者: Pan, SL
关键词: Pb3Cd3(BO3)(4) ; Borate ; Synthesis ; Crystal structure ; Optical property
刊名: INORGANICA CHIMICA ACTA
发表日期: 2012
DOI: 10.1016/j.ica.2011.11.059
卷: 384, 期:4, 页:158-162
收录类别: SCI
资助者: Chinese Academy of Sciences KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; Scientific Research Program of Urumqi of China G09212001
摘要: A new ternary borate, Pb3Cd3(BO3)(4), has been synthesized by solid-state reaction at 530 degrees C. The compound crystallizes in the hexagonal space group P6(3)/m with a = 9.946(4), c = 7.003(5) angstrom, and Z = 2. The crystal structure consists of one-dimensional (1D) long PbO5(infinity) tubes. The tubes are further connected by BO3 to generate a three-dimensional framework with the six-member tunnels along the c axis, where Cd atoms locate and the CdO6 octahedra form 1D chain. The IR spectrum confirms the presence of BO3 unit. The UV-Vis-IR diffuse reflectance spectrum exhibits a band gap of about 3.56 eV. The DSC analysis suggests that Pb3Cd3(BO3)(4) is an incongruent melting compound.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1631
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Yu Hongwei,Pan Shilie,Wu Hongping,et al. Synthesis, structure characterization and optical properties of a new lead cadmium borate[J]. INORGANICA CHIMICA ACTA,2012,384(4):158-162.
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